相关实验视频
Updated: Jul 19, 2025

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Measuring the Densities of Aqueous Glasses at Cryogenic Temperatures
Published on: June 28, 2017
8.8K
在从环境温度快速降温时,水的结构松
Loni Kringle1, Bruce D Kay1, Greg A Kimmel1
1Physical Sciences Division, Pacific Northwest National Laboratory, P.O. Box 999, Richland, Washington 99352, USA.
The Journal of chemical physics
|August 8, 2023
概括
研究深度超冷水需要了解其结构. 超冷却水 (HQW) 在快速冷却后保留了显著的高温水结构,有助于超冷却水研究.
科学领域:
- 物理化学 物理化学
- 材料科学 材料科学 材料科学
- 热力学是一种热力学.
背景情况:
- 了解水的异常特性需要研究深度超冷状态.
- 纳米级水膜的短暂加热和快速火提供了对这些状态的见解.
研究的目的:
- 量化过度冷却水 (HQW) 对低密度无形 (LDA) 冰的结构放松.
- 确定HQW结构如何与不同温度的平衡水结构有关.
主要方法:
- 红外反射吸收光谱法用于分析LDA,HQW和晶体冰膜.
- 从光谱数据确定了复杂的折射指数.
- 纳入了水和无形冰的X射线衍射数据.
主要成果:
- 过度灭水 (HQW) 保留了大约50%-60%的高温水结构图案.
- 在HQW的剩余结构是低温图案的特征.
- 高温图案的部分被量化为零压力温度 (150-350K) 的函数.
结论:
- HQW为研究超冷水的结构动态提供了有价值的探测器.
- 该方法允许在水状态下量化结构图案.
- 这项研究有助于全面了解水的相位行为.
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