从超快的增长到在去除玻璃的雪崩式增长
Taiki Yanagishima1, John Russo2, Roel P A Dullens3
1Department of Physics, Graduate School of Science, Kyoto University, Kitashirakawa Oiwake-cho, Sakyo-ku, Kyoto 606-8502, Japan.
The Journal of chemical physics
|August 8, 2023
概括
玻璃制备方法决定了除玻璃化模式. 传统的玻璃 (CG) 显示出快速的晶体生长,而统一的玻璃 (UG) 显示出更慢的雪崩般的生长,揭示了晶体形成的关键因素.
科学领域:
- 材料科学 材料科学 材料科学
- 凝聚物质物理学 凝聚物质物理学
- 计算化学的计算化学
背景情况:
- 脱涉及通过扩散或快速晶体生长模式的晶体体生长.
- 影响晶体生长模式和预测的因素仍然不清楚.
研究的目的:
- 研究玻璃制备协议如何影响除玻璃化模式.
- 确定不同晶体生长行为的潜在机制.
主要方法:
- 排斥性硬球状 (维克斯-钱德勒-安德森) 眼镜的模拟.
- 通过快速火制备常规玻璃 (CG),通过密度均化制备均玻璃 (UG).
- 在能源最小化和热噪声下分析玻璃晶接口 (CGX/UGX).
主要成果:
- 同一个玻璃系统可以根据制备表现出快速和扩散性脱玻璃化模式.
- 传统玻璃 (CG) 显示出深层晶体透和增强的界面动态,与快速生长相关.
- 均玻璃 (UG) 显示最小的晶体生长,具有局部的,间歇性的雪崩般的动态.
结论:
- 玻璃制备协议是去玻璃化模式的关键决定因素.
- 观察到的晶体生长动态的差异与界面特性和玻璃结构有关.
- 这些发现提供了对低于玻璃过渡温度的晶体生长实验观测的见解.
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