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Updated: Jul 19, 2025

Author Spotlight: Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers
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两个3D双重互通的像多氧甲酸盐的金属有机框架:合成和硫化物选择性氧化活动

Xue Bai1, Xu Han1, Yuxin Wang1

  • 1Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education, College of Chemistry, Northeast Normal University, Changchun, Jilin 130024, P. R. China.

Inorganic chemistry
|August 8, 2023
PubMed
概括

基于多氧甲酸盐的两种新型金属有机框架 (POMOF) 在硫化物氧化反应中表现出良好的催化活性和选择性. 这些可回收的POMOF提供了可持续和高效的催化剂,用于使用过氧化生产硫氧化物.

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Preparation and Reactions of Sulfides02:26

Preparation and Reactions of Sulfides

Sulfides are the sulfur analog of ethers, just as thiols are the sulfur analog of alcohol. Like ethers, sulfides also consist of two hydrocarbon groups bonded to the central sulfur atom. Depending upon the type of groups present, sulfides can be symmetrical or asymmetrical. Symmetrical sulfides can be prepared via an SN2 reaction between 2 equivalents of an alkyl halide and one equivalent of sodium sulfide.
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