从酸性溶液中选择性吸附和回收银,使用生物质衍生硫添加的多孔碳
Jinlong Fan1, Li Duan1, Xiangbo Zhang1
1Northwest Institute of Nuclear Technology, Xi'an, Shaanxi 710024, China.
ACS applied materials & interfaces
|August 9, 2023
概括
从废弃物中回收银,使用来自激情果的S-doped多孔碳 (SPC). 这些环保吸附剂在从酸性溶液中回收银方面具有很高的容量和选择性.
科学领域:
- 材料科学 材料科学 材料科学
- 环境化学环境化学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 天然资源有限,需要有效回收废物流中的贵金属,如银.
- 开发可持续和高效的吸附剂对于资源回收至关重要.
研究的目的:
- 为了合成和研究来自激情果的S-化多孔碳 (SPCs) 进行银离子 (Ag+) 吸附.
- 评估从酸性溶液中回收Ag+的SPC的吸附能力,动力学和选择性.
主要方法:
- 用水热碳化和KOH/NH4) 2SO4激活来合成SPCs.
- 在酸性条件下进行了Ag+吸附实验.
- 吸附数据使用伪二次动力学和Langmuir异热模型进行分析.
主要成果:
- 激活剂 (NH4) 2SO4引入了硫注射,并增加了SPC中的中性.
- 优化的SPC-3表现出最大的Ag+吸附能力为115mg/g在0.5mol/L的HNO3.
- 由于硫的功能组形成Ag2S纳米粒子,SPC显示出对Ag+的高选择性,而不是其他离子.
结论:
- 从激情果中提取的S-doped多孔碳是银回收的有效吸附剂.
- S-doping和多孔结构提高了Ag+吸附性能.
- 回收的白银可以通过化在基本形式获得,提供可持续的回收途径.
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