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使用拉曼微光谱学对人为酸盐的结晶性评估
Michael B Toffolo1, Iddo Pinkas2, Ana Álvaro Gallo3
1Geochronology and Geology Program, Centro Nacional de Investigación sobre la Evolución Humana (CENIEH), Paseo Sierra de Atapuerca 3, 09002, Burgos, Spain. michael.toffolo@cenieh.es.
Scientific reports
|August 10, 2023
概括
人类产生的石,在材料中发现,如结合剂,具有较低的结晶度比自然石. 拉曼光谱,使用带宽,可以有效地区分这些石,帮助考古学研究.
科学领域:
- 地质化学 地质化学
- 材料科学 材料科学 材料科学
- 考古测量考古测量方法
背景情况:
- 人类产生的石是粘剂和木灰中的关键成分,由于形成过程不同,它与地质产生的石有很大的不同.
- 这种差异主要在于它们的结晶度,而人为石的结晶度较低.
研究的目的:
- 调查拉曼微光谱技术在评估石结晶性方面的潜力.
- 建立一个参考框架,使用拉曼光谱来区分人类产生的和地球产生的酸盐.
- 将这些发现应用于分析考古石灰粘合剂.
主要方法:
- 在传输模式下使用红外 (IR) 光谱法来建立石结晶性的独立参考.
- 拉曼微光谱法被用来分析石带的半最大 (FWHM) 的全宽度.
- 拉曼波段的FWHM与来自IR的结晶度参考值相关.
主要成果:
- 拉曼光谱中带宽被证实是石结晶性的可靠代理.
- 在人类产生的和地球产生的石样本之间观察到结晶度的明显区别.
- 该方法成功地被应用在考古石灰粘合剂中,以不同的保存状态来评估人为石的结晶性.
结论:
- 拉曼微光谱,特别是带宽的分析,提供了一种有效的方法来区分人为和地质石.
- 这种技术为考古材料的形成过程和保存状态提供了宝贵的见解,如结合剂.
- 拉曼光谱的进一步发展可以提高其在考古学和材料科学中的应用.
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