通过反透屏障证明回收水中新出现的污染物的去除信用-一个预测框架
Hongjiao Pang1, Mayumi Allinson1, Kathy Northcott2
1Department of Chemical Engineering, The University of Melbourne, Parkville, Melbourne, VIC 3010, Australia.
Water research
|August 11, 2023
概括
反透 (RO) 系统的性能对于新出现的污染物 (CEC) 不同. 本研究验证了CEC的RO日志减少值 (LRV) 信用,建立了回收水中的化学风险管理框架.
科学领域:
- 环境科学 环境科学
- 水处理技术水处理技术
- 化学工程是化学工程的重要组成部分.
背景情况:
- 反透 (RO) 系统的性能与不同的新兴关注污染物 (CEC) 有显著差异.
- 对于CEC的日志减少值 (LRV) 不能在没有系统验证的情况下在水处理和回收中任意使用.
- 化学风险管理需要对不同CEC的RO障碍性能有明确的了解.
研究的目的:
- 通过系统地验证各种CEC类的LRV信贷的RO障碍性能来提出管理化学风险的方法.
- 开发和验证一个框架来预测RO膜在操作条件下消除广泛的CEC的性能.
- 评估导电性和生物测试作为RO性能和水毒性指标的适用性.
主要方法:
- 在一家大型水回收工厂进行了一次性采样活动,跨越五个处理障碍 (过器过,超过,RO,离子交换,化).
- 进行了系统的六周抽样活动,重点关注RO屏障.
- 使用GC-MS量化948种微量有机化学品,使用LC-MS/MS量化44种和多基物质 (PFAS) 来确定RO去除信用.
主要成果:
- 验证了LRV障碍信用框架,以预测在典型运行条件下各种化学品类的聚胺RO膜性能.
- 作为膜完整性和RO性能的有效替代品,证明了导电性,与透流量和回收率相关.
- 鉴定了光细菌生物测试作为一种潜在的快速,具有成本效益的方法,用于指示一般化学污染的毒性,因为它的灵敏度和效率.
结论:
- 该研究提供了一种系统的方法,以验证LRV信用的RO屏障性能,这对于精确的化学风险管理在水回收至关重要.
- 导电性和特定的操作参数是RO膜完整性和性能的可靠指标.
- 生物测试方法显示出化学污染水样本中快速毒性评估的前景.
更多相关视频
09:49Use of a Battery of Chemical and Ecotoxicological Methods for the Assessment of the Efficacy of Wastewater Treatment Processes to Remove Estrogenic Potency
Published on: September 11, 2016
14.1K
07:55Ion-Exchange Membranes for the Fabrication of Reverse Electrodialysis Device
Published on: July 20, 2021
10.7K
相关概念视频
Coagulation
329
Colloidal solids are solid particles suspended in solution. They are usually negatively charged, attracting a compact primary layer of positively charged ions, which attract more counterions to form an electrical double layer. Electrostatic repulsion between the charged double layers prevents the particles from colliding, stabilizing the colloids. These solids are often undesirable because they can contain toxins that are difficult to remove. Coagulation is a technique that helps aggregate and...
329
Bioremediation
19.0K
Bioremediation is the use of prokaryotes, fungi, or plants to remove pollutants from the environment. This process has been used to remove harmful toxins in groundwater as a byproduct of agricultural run-off and also to clean up oil spills.
19.0K
Precipitation and Co-precipitation
1.9K
Precipitation and coprecipitation methods can be used to separate a mixture of ions in a solution. In qualitative inorganic analysis, ions that form sparingly soluble precipitates with the same reagent are separated based on the differences in solubility products. For example, consider the separation of Cu(II) and Fe(II) ions by precipitation as insoluble sulfides. First, copper(II) sulfide is precipitated by the addition of acidic H2S, where the dissociation of H2S is suppressed. Adding H2S...
1.9K
Factors Affecting Solubility
33.5K
Compared with pure water, the solubility of an ionic compound is less in aqueous solutions containing a common ion (one also produced by dissolution of the ionic compound). This is an example of a phenomenon known as the common ion effect, which is a consequence of the law of mass action that may be explained using Le Chȃtelier’s principle. Consider the dissolution of silver iodide:
33.5K
