在工业固体废物炼渣中同步稳定Pb,Zn,Cd和As
Qiwei Sun1, Huifen Yang1, Xiaodi Feng1
1School of Civil and Resource Engineering, University of Science and Technology Beijing, Beijing, 100083, China.
Chemosphere
|August 11, 2023
概括
这项研究表明,石油污泥热解残留物和飞灰的混合物有效地稳定了炼渣中的重金属. 这项环保修正案减少了污染,并提供了有利可图的废物管理解决方案.
科学领域:
- 环境科学 环境科学
- 地质化学 地质化学
- 材料科学 材料科学 材料科学
背景情况:
- 化渣 (LSS) 由于重金属 (HM) 的污染,造成环境风险.
- 工业固体废物,如飞 (FA),油泥热解残留物 (PR) 和钢 (SS) 是潜在的整治修正案.
研究的目的:
- 研究使用FA,PR和SS来稳定LSS中的HM的可行性,影响因素和机制.
- 确定最佳的修改组合,以有效地修复HM,并评估其经济可行性.
主要方法:
- 研究了材料剂量,含水量和LSS颗粒大小对稳定性的影响.
- 评估了单个修改和联合PR2FA1修改 (2:1质量比) 的性能.
- 利用形态分析,显微镜表征和模拟溶液吸附实验来了解稳定机制.
主要成果:
- 综合修改PR2FA1证明了LSS中As,Zn,Cd和Pb的优异稳定性,显著降低了漏度.
- 液的pH值保持在表面水质 (第四类) 的可接受范围内.
- 稳定机制包括静电吸引,物理吸附,离子交换和化学沉,由PR2FA1的活性成分和多孔结构促进.
结论:
- PR2FA1有效地固定了LSS中的HM,减轻了环境污染.
- 这种方法为危险的石油污泥提供了一种安全而富有资源的处置方法.
- PR2FA1的成本效益表明,在废物整治中具有强大的商业应用潜力.
更多相关视频
相关概念视频
Washing, Drying, and Ignition of Precipitates
951
After filtration, the precipitate is washed to remove coprecipitated impurities and any remaining mother liquor. Colloidal precipitates, such as silver chloride, are washed with an electrolyte (such as dilute nitric acid) to prevent the peptization of the precipitate. In the case of slightly soluble precipitates, the wash solution contains a common ion to reduce solubility. Lead sulfate, which is slightly soluble in water, is washed with dilute sulfuric acid. Similarly, wash solutions may be...
951
Steel Manufacturing
623
Steel manufacturing is a multi-stage process that begins by smelting iron ore into cast iron in a blast furnace. This initial stage involves layering iron ore with coke, a type of fuel, and crushed limestone within the furnace. The coke is ignited with a high volume of air, leading to the creation of carbon monoxide, which acts to reduce the iron ore to pure iron.
During this smelting process, limestone plays a crucial role by forming slag. Slag captures impurities within the molten iron, such...
During this smelting process, limestone plays a crucial role by forming slag. Slag captures impurities within the molten iron, such...
623
Sample Preparation for Analysis: Advanced Techniques
391
Accurate analysis of complex samples often requires advanced preparation techniques to achieve reliable and reproducible results. Samples containing inorganic or organic materials can be challenging to dissolve or decompose effectively. Standard sample preparation methods include acid digestion, fusion, dry ashing, and wet digestion.
Acid digestion with strong acids is commonly used to dissolve inorganic materials that are insoluble (do not dissolve) in water. This method can be useful for...
Acid digestion with strong acids is commonly used to dissolve inorganic materials that are insoluble (do not dissolve) in water. This method can be useful for...
391
Precipitation and Co-precipitation
1.9K
Precipitation and coprecipitation methods can be used to separate a mixture of ions in a solution. In qualitative inorganic analysis, ions that form sparingly soluble precipitates with the same reagent are separated based on the differences in solubility products. For example, consider the separation of Cu(II) and Fe(II) ions by precipitation as insoluble sulfides. First, copper(II) sulfide is precipitated by the addition of acidic H2S, where the dissociation of H2S is suppressed. Adding H2S...
1.9K
Coagulation
329
Colloidal solids are solid particles suspended in solution. They are usually negatively charged, attracting a compact primary layer of positively charged ions, which attract more counterions to form an electrical double layer. Electrostatic repulsion between the charged double layers prevents the particles from colliding, stabilizing the colloids. These solids are often undesirable because they can contain toxins that are difficult to remove. Coagulation is a technique that helps aggregate and...
329


