在两个对比的分层湖的氧表面水层中,甲和其潜在的前体化合物的积累
Moritz Schroll1, Liu Liu2, Teresa Einzmann3
1Laboratory of Plateau Geographical Processes and Environmental Changes, Faculty of Geography, Yunnan Normal University, 650500 Kunming, China; Institute of Earth Sciences, Heidelberg University, 69120 Heidelberg, Germany.
The Science of the total environment
|August 11, 2023
概括
氧化湖水中的甲超和是由复杂的过程驱动的,而不仅仅是无氧条件. 这项研究显示,甲基酸盐和甲基胺等关键前体有助于甲积累,影响大气排放.
科学领域:
- 环境科学 环境科学
- 地质化学 地质化学
- 临界技术 临界技术
背景情况:
- 含氧水中的甲 (CH4) 超和挑战了传统的甲生成观点,认为甲生成只发生在无氧环境中.
- 虽然已知一些氧化CH4的生产机制,但它们在淡水湖中的时间变化和驱动因素仍然不太清楚.
- 了解氧化湖层中的CH4动态对于预测其大气排放至关重要.
研究的目的:
- 从2019年到2020年,调查德国两个对比的湖泊 (Willersinnweiher湖和Stechlin湖) 的氧化水层中CH4的季节性积累.
- 探索CH4同位素值的动态,并确定潜在的前体化合物,负责氧化CH4的生产.
- 阐明控制CH4超和和积在淡水生态系统中的过程的相互作用.
主要方法:
- 在两个湖泊的地表水和热层中实地监测CH4度和同位素值 (13C-CH4和2H-CH4).
- 使用13C和2H标记的甲基化P,N和C化合物的化实验,以确定CH4前体.
- 分析CH4积累的时间变化以及与环境因素和前体可用性的相关性.
主要成果:
- 在地表水中观察到持续的CH4超和,主要是在热点线周围,有显著的季节性变化.
- CH4积累在浅层的维勒辛纳威海湖中通常比深层的斯特赫林湖更为明显.
- CH4度的增加与13C-CH4和2H-CH4的丰富相关,表明CH4氧化,运输和氧化生产的组合.
- 甲基酸盐,甲基胺和甲因被确定为在有氧湖水中维持CH4超和的强有力的前体.
结论:
- 淡水湖中的氧化CH4的产生和积累是由各种过程维持的,包括利用特定的甲基化化合物.
- 来自浮游生物的前体在支持氧化湖层中CH4的产生中发挥着重要作用.
- 进一步研究CH4的生产和运输途径,包括前体动态,对于准确预测水中CH4排放至关重要.
相关概念视频
The Water Cycle
24.5K
The Earth’s hydrosphere includes all of the areas where the storage and movement of water occurs. Since water is the basis of all living processes, the cycling of water is extremely important to ecosystem dynamics.
24.5K
Gravimetry: Inorganic And Organic Precipitating Agents
1.3K
In gravimetry, the precipitant is chosen carefully to obtain a pure solid that can be easily filtered. Common inorganic precipitants can be used to determine several cations and anions. In some cases, the formation of the same precipitate can be used to determine the cation and the anion. For example, the reaction of barium and chromate ions to give barium chromate is used to determine both barium and chromate. However, precipitates such as hydroxides, oxalates, and metal ammonium phosphates...
1.3K
Primary Production
23.7K
The total amount of energy acquired by primary producers in an ecosystem is called gross primary production (GPP). However, of this energy, producers use some for metabolic processes, and some is lost as heat, decreasing the amount of energy available to the next trophic level. The remaining usable amount of energy is called the net primary productivity (NPP). In terrestrial ecosystems, NPP is driven by climate, while light penetration and nutrient availability drive NPP in aquatic ecosystems.
23.7K


