纤维素宏纤维素的分离及其对结合水的影响
Thaddeus Maloney1, Josphat Phiri1, Aleksi Zitting1
1Department of Bioproducts and Biosystems, School of Chemical Engineering, Aalto University, P.O. Box 16300, 00076 Aalto, Finland.
Carbohydrate polymers
|August 11, 2023
概括
使用静电相互作用和透压力控制纸纤维膨胀,显著增加了纤维表面积和中等尺度膨胀. 这种等级控制为增强纤维产品的强度和密度提供了一个有希望的方法.
科学领域:
- 材料科学 材料科学 材料科学
- 合体和表面化学
- 生物材料工程 生物材料工程
背景情况:
- 纸纤维的胀对于材料性能至关重要.
- 了解层次性胀是优化纤维制品的关键.
- 静电相互作用和透压是潜在的控制机制.
研究的目的:
- 为了控制和测量纸纤维的等级胀.
- 为了研究静电相互作用和局部透压的作用.
- 探索酸盐组增加对纤维特性的影响.
主要方法:
- 采用了优性溶剂系统来修改细胞壁的化学成分.
- 系统地增加了酸盐组和纤维电荷.
- 采用了X射线散射,溶解物排除和一种新的温度测量方法.
主要成果:
- 增加的纤维电荷增强了胀特性.
- 宏纤维素脱发生在180-200μmol/g的电荷下,增加胀 (0.9到2.5mL/g) 和表面积 (400到1000m2/g).
- 含水面积在1200-1400 m2/g之间,与模拟相一致.
结论:
- 通过静电相互作用对纤维胀的层次控制是可行的.
- 宏纤维素脱聚是影响胀和表面积的关键事件.
- 这种方法有可能提高包装和其他纤维产品的强度/密度.
相关概念视频
Cellulose and Pectic Polysaccharides
3.6K
Every plant cell has a cell wall that protects the cell, provides structural support, and gives the cell shape. Cellulose, the main structural component of the plant cell wall, makes up over 30% of plant matter. It is the most abundant organic compound on earth. Cellulose is an unbranched polysaccharide composed of linear chains of glucose molecules linked by β (1→4) glycosidic bonds.
As a cell matures, its cell wall specializes according to its type. For example, the...
As a cell matures, its cell wall specializes according to its type. For example, the...
3.6K
Role of Microtubules in Cell Wall Deposition
2.4K
Microtubules are small hollow tubes in eukaryotic cells. The cell wall microtubules are polymerized dimers of two globular proteins, α-tubulin and β-tubulin, two globular proteins. With a diameter of about 25 nm, microtubules are the widest components of the cytoskeleton. They help the cell resist compression and provide a track along which vesicles move through the cell or pull replicated chromosomes to opposite ends of a dividing cell. Microtubules go through quick cycles of...
2.4K
Adhesion
40.0K
Adhesion occurs when one type of molecule is attracted to a different molecule. Water exhibits adhesive properties in the presence of polar surfaces, such as glass or cellulose in plants. For instance, when water is poured into a glass, the positively charged hydrogen molecules of water are more attracted to the negatively charged oxygen molecules in the silica than to the oxygen in neighboring water molecules.
Capillary action is a result of water’s adhesive tendencies. When a narrow...
Capillary action is a result of water’s adhesive tendencies. When a narrow...
40.0K
Hydrolysis
105.7K
Overview
Hydrolysis is a chemical reaction in which the addition of water breaks down a polymer into its simpler monomer units. For example, peptides break into amino acids, carbohydrates into simple sugars, and DNA into nucleotides. Enzymes often facilitate these processes.
Hydrolysis Reverses Dehydration Synthesis
Complex carbohydrates can be broken down by breaking the bonds between individual sugar units. The reaction breaks a glycosidic bond as water is added to the compound. The...
Hydrolysis is a chemical reaction in which the addition of water breaks down a polymer into its simpler monomer units. For example, peptides break into amino acids, carbohydrates into simple sugars, and DNA into nucleotides. Enzymes often facilitate these processes.
Hydrolysis Reverses Dehydration Synthesis
Complex carbohydrates can be broken down by breaking the bonds between individual sugar units. The reaction breaks a glycosidic bond as water is added to the compound. The...
105.7K
Chemistry of Carbohydrates
73.1K
Carbohydrates are an essential part of the diet in humans and animals. Grains, fruits, and vegetables are natural sources of carbohydrates that provide energy to the body, particularly through glucose, a simple sugar that is a component of starch and an ingredient in many staple foods. The stoichiometric formula (CH2O)n, where n is the number of carbons in the molecule represents carbohydrates. In other words, the ratio of carbon to hydrogen to oxygen is 1:2:1 in carbohydrate molecules. This...
73.1K


