基于水泥的材料在低温海水中的恶化
Mari Kobayashi1, Keisuke Takahashi1, Yuichiro Kawabata2
1Mitsubishi UBE Cement Corporation, 1-6 Okinoyama, Yamaguchi 755-8633, Japan.
Materials (Basel, Switzerland)
|August 12, 2023
概括
低温海水显著破坏水泥材料,导致表面崩和化学变化. 这项研究强调了寒冷环境中对海洋基础设施的风险.
科学领域:
- 材料科学 材料科学 材料科学
- 土木工程 土木工程是指土木工程.
- 海洋科学 海洋科学
背景情况:
- 水泥材料对于海洋基础设施至关重要.
- 海洋的恶化已知,但温度的影响尚不清楚.
- 低温环境带来了独特的挑战.
研究的目的:
- 为了研究低温海水对水泥耐用性的影响.
- 阐明寒冷海洋条件下恶化的机制.
主要方法:
- 水泥糊样本在2°C和室温的海水中浸泡了433天.
- 对受损样本进行视觉检查和化学分析.
主要成果:
- 在2°C海水中的标本显示了显著的表面崩.
- 低温浸泡增加了的溶解.
- 脱的 () 酸盐水合物 (C- (((A-) S-H), () 酸盐水合物 (M- (((A-) S-H) 和陶马石形成.
结论:
- 低温增加了波特兰的溶解度,导致Ca溶解和C-A-) S-H脱.
- 形成M-(A-) S-H和thaumasite有助于恶化.
- 这些发现对于在寒冷的海洋环境中设计耐用的水泥结构至关重要.
更多相关视频
10:00Experimental Protocol to Determine the Chloride Threshold Value for Corrosion in Samples Taken from Reinforced Concrete Structures
Published on: August 31, 2017
15.5K
06:27Sandy Soil Improvement through Microbially Induced Calcite Precipitation MICP by Immersion
Published on: September 12, 2019
9.5K
相关概念视频
Effect of Sea Water on Concrete
284
Concrete exposed to seawater can undergo degradation like the dissolution of ettringite and gypsum, increasing the material's porosity and decreasing its strength. In contrast, the crystallization of salts within the concrete's pores can cause expansion, particularly above the waterline where evaporation occurs. Nonetheless, this expansion only happens when seawater, enabled by the concrete's permeability, manages to infiltrate the structure.
Concrete in areas between tide marks,...
Concrete in areas between tide marks,...
284
Acid Attack on Concrete
248
When acids come into contact with concrete, they initiate a chemical reaction that dissolves the hydrated cement paste. This process leads to softening and structural weakening of the concrete. This issue is commonly observed in environments such as chimneys, sewers, and industrial settings. The severity of the damage increases as the pH of the water interacting with the concrete drops below 6.5. In particular, a pH under 4.5 can cause significant concrete damage.
The rate at which hydrogen...
The rate at which hydrogen...
248
Sulfate Attack on Concrete
185
Sulfate attack on concrete is a deterioration process characterized by a whitish discoloration beginning at the edges and corners, accompanied by cracking and spalling. This phenomenon occurs when sulfates react with the components of hardened concrete, forming compounds like calcium sulfate and calcium sulfoaluminate which occupy more space than the substances they replace, causing the concrete to expand and disrupt.
Sulfates from sources like soil, groundwater, or industrial effluents...
Sulfates from sources like soil, groundwater, or industrial effluents...
185
Corrosion of Reinforcement
215
The corrosion of steel reinforcement within concrete is a process influenced by the material's inherent properties and external factors. The high pH level of around 13, provided by calcium hydroxide present in concrete, initially protects the steel reinforcement by promoting the formation of a passive iron oxide layer on its surface.
However, over time and under certain conditions like carbonation, chloride ingress, and cracking this protective state can be compromised. Steel has areas with...
However, over time and under certain conditions like carbonation, chloride ingress, and cracking this protective state can be compromised. Steel has areas with...
215
Types of Cement I
150
Portland cement comes in several types, each with distinct properties and applications based on their chemical composition and hydration characteristics:
Type I (Ordinary Portland Cement) is widely used for general construction where special properties are not required. It has moderate sulfate resistance and heat of hydration.
Type II (Modified Cement) offers moderate resistance to sulfate attack and a lower rate of heat development compared to Type I. It is suitable for structures in...
Type I (Ordinary Portland Cement) is widely used for general construction where special properties are not required. It has moderate sulfate resistance and heat of hydration.
Type II (Modified Cement) offers moderate resistance to sulfate attack and a lower rate of heat development compared to Type I. It is suitable for structures in...
150
Carbonation Shrinkage
165
Atmospheric CO2 penetrates the concrete's pores and, in the presence of moisture, forms carbonic acid, which then reacts with calcium hydroxide in the hydrated cement, forming calcium carbonate. This process reduces the concrete's volume and is termed carbonation shrinkage.
The concrete's permeability is slightly reduced as calcium carbonate produced during the reaction fills its pores. Furthermore, its strength is slightly enhanced as the water released during the reaction...
The concrete's permeability is slightly reduced as calcium carbonate produced during the reaction fills its pores. Furthermore, its strength is slightly enhanced as the water released during the reaction...
165
