在基于水泥的酸砂中固定Al/Mg合金的电化学行为
Gabriel Poras1, Céline Cau Dit Coumes1, Pascal Antonucci1
1CEA, DES, ISEC, DPME, SEME, LFCM, Université de Montpellier, 30207 Bagnols-sur-Cèze, France.
Materials (Basel, Switzerland)
|August 12, 2023
概括
酸 (MKP) 水泥为波特兰水泥提供了一个优质的替代品,用于稳定放射性废物中的-合金. MKP水泥随着时间的推移显著减少合金腐蚀,减轻危险的二气体释放.
科学领域:
- 材料科学 材料科学 材料科学
- 核工程 核工程是指核工程.
- 化学工程是化学工程的重要组成部分.
背景情况:
- 波特兰水泥广泛用于放射性废物稳定,具有较高的性.
- 这种性阻碍了由于氧化和二气体生产而导致的金属废物的稳定.
- - (Al-Mg) 合金是放射性废物流中的常见杂质.
研究的目的:
- 评估酸 (MKP) 水泥作为Al-Mg合金废物稳定的替代粘合剂.
- 评估Al-Mg合金组成对水泥基质反应性的影响.
- 为了比较MKP中的Al-Mg合金与波特兰水泥的长期腐蚀性能.
主要方法:
- 气相色谱 (GC) 用于量化合金腐蚀释放的二.
- 电化学阻抗光谱 (EIS) 用于评估腐蚀动力学和电流.
- 在MKP和波特兰水泥基层中制备和测试Al-Mg合金一年多.
主要成果:
- 释放的二独立于Al-Mg合金中的含量.
- EIS提供了与反应机制相关的定量腐蚀电流数据.
- 与波特兰水泥砂相比,Al-Mg合金的腐蚀电流在一年内在MKP砂中减少了近三倍.
结论:
- 与波特兰水泥相比,MKP水泥在降低Al-Mg合金腐蚀方面表现优越.
- MKP水泥是稳定含有Al-Mg合金的放射性废物的有希望的替代粘合剂.
- 减少MKP中的腐蚀可以最大限度地减少危险的二气体的演化,从而提高废物安全.
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