一种基于Zn的状协调聚合物,在脱水后显示增加光发光
Oier Pajuelo-Corral1, Jose Angel García2, Oscar Castillo3,4
1Departamento de Química Aplicada, Facultad de Química, Universidad del País Vasco/Euskal Herriko Unibertsitatea (UPV/EHU), 20018 Donostia, Spain.
Molecules (Basel, Switzerland)
|August 12, 2023
概括
使用无溶剂方法合成了一种新的2D协调聚合物{[Zn(pmdc) ((H2O) ]·H2O}n. 这种材料表现出由脱水和温度变化影响的光发光特性.
科学领域:
- 材料科学 材料科学 材料科学
- 无机化学 无机化学 有机化学
- 晶体学 晶体学是指结晶学.
背景情况:
- 协调聚合物 (CPs) 为各种应用提供可调节的特性.
- 对于绿色化学和减少副产品,无溶剂合成方法是可取的.
研究的目的:
- 为了合成和表征一种新的2D片状协调聚合物,使用pyrimidine-4,6-dicarboxylate (pmdc).
- 研究合成的CP的结构,热和光发光特性.
- 探索脱水和温度对材料的排放能力的影响.
主要方法:
- 没有溶剂的固态合成.
- 进行X射线晶体结构分析.
- 热重力测量分析 (TGA) 和热衍射测量.
- 光发光光谱学. 光发光光谱学.
- 时间依赖密度功能理论 (TD-DFT) 的计算.
主要成果:
- 一种二维状协调聚合物{[Zn(μ3-pmdc) ((H2O) ]·H2O}n被成功合成.
- 晶体结构揭示了Zn2实体,形成六个组成的环状层,通过键连接.
- 该化合物表现出光发光,其特性由脱水和温度下降调节.
- TD-DFT计算提供了对光谱特征的见解.
结论:
- 开发的无溶剂方法对于合成协调聚合物是有效的.
- 合成的CP表现出有趣的结构和光发光特性.
- 该材料的光发光度对脱水和温度等环境变化很敏感,这表明了潜在的应用.
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