使用功能化的硫酸盐基离子液去除:水过系统应用
Ain Aqilah Basirun1, Wan Azlina Wan Ab Karim2, Ng Cheah Wei3
1Centre of Research in Ionic Liquids (CORIL), Institute of Contaminant Management (ICM), Universiti Teknologi PETRONAS, Seri Iskandar 32610, Perak, Malaysia.
Molecules (Basel, Switzerland)
|August 12, 2023
概括
这项研究开发了一种新的水凝吸附剂,用于从工业废水中去除有毒 (Mn). 在PVA-酸珠中的功能化硫酸盐基离子液体实现了超过98%的Mn去除效率.
科学领域:
- 环境化学环境化学
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 工业废水通常含有有毒的重金属,如 (Mn),造成严重的环境和健康风险.
- 传统的处理方法可能是低效或昂贵的,需要开发先进的整治技术.
- 离子液体具有独特的吸附性能,但它们在废水处理中的应用需要稳定且可重复使用的矩阵.
研究的目的:
- 合成和描述一种新型的聚合物水凝吸附剂,用于有效地从工业废水中去除.
- 为了研究功能化硫酸盐基离子液体的吸附性能,将其纳入聚乙烯醇 (PVA) - 酸珠.
- 优化吸附过程参数,评估材料的可重复使用性和工业适用性.
主要方法:
- 一种功能化的基于硫酸盐的离子液 (1-hexylimidazole propionitrile thiosalicylate, [HIMP][TS]) 被合成并固定在PVA-alginate珠子上.
- 使用里埃变换红外光谱 (FTIR) 和场发射扫描电子显微镜 (FESEM) 进行了结构性表征.
- 使用原子吸收光谱 (AAS) 量化了的度和去除效率,并通过Box-Behnken设计优化了工艺.
主要成果:
- PVA-酸-[HIMP][TS]珠子显示出高结构完整性和有效的吸附.
- 去除的最佳条件是pH7.15,60分钟接触时间和38.26g/L的吸附剂剂量,达到98.91%的去除效率.
- 吸附剂在原型过系统中表现出色 (99.14%的去除率),并在四个再生周期中保持高效率,吸附能力为56 mg/g.
结论:
- 开发的基于酸盐-硫酸盐的离子液体系统是一种高效和环保的吸附剂,用于从工业废水中去除.
- 由于其高效率,可重复使用性和稳定性,PVA-酸-[HIMP][TS]珠子显示出实际工业应用的巨大潜力.
- 这项研究提出了一种有希望的重金属修复方法,有助于清洁工业流程和环境保护.
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