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来自果皮的生物相容和生物降解表面活性剂用于石油泄漏整治

Peng Soon Wang¹, Aqeel Ahmad¹, Masooma Nazar¹

¹Department of Chemical Engineering, Universiti Teknologi PETRONAS, Seri Iskandar 32610, Perak, Malaysia.

Molecules (Basel, Switzerland)

|August 12, 2023

概括

皮中的两种新生物降解表面活性剂SOPIL和SOPOS在石油泄漏整治方面表现有前途. 索皮尔 (SOPIL) 证明了卓越的分散效率和最小的毒性,为传统表面活性剂提供了可持续的替代品.

科学领域:

环境化学环境化学
绿色化学绿色化学
材料科学材料科学材料科学

背景情况:

石油泄漏对环境构成重大威胁,需要有效的补救策略.
在整治中使用的常规化学表面活性剂通常是有毒的和不可生物降解的.
迫切需要可持续和环保的替代品.

研究的目的:

从子皮废物中合成和评估生物相容和可生物降解的表面活性剂.
用离子液体 (SOPIL) 和有机溶剂 (SOPOS) 作为反应介质合成的表面活性剂的性能进行比较.
评估这些新型表面活性剂的环境安全性和有效性,用于石油泄漏整治.

主要方法:

使用皮,1--3-甲基化 (BMIMCl) 和二甲基胺的表面活性剂合成.
表面活性剂性能的表征,包括表面张力,分散剂有效性 (混瓶试验) 和乳液稳定性.
使用斑马鱼 (Danio rerio) 的急性毒性和通过闭瓶试验 (CBT) 的生物降解性的评估.

主要成果:

索皮尔的临界菌度 (8.57毫克/升) 比索波斯 (9.42毫克/升) 低.
与SOPOS (40.30%) 相比,SOPIL显示出明显更高的分散效率 (69.78%).
索皮尔被归类为"几乎无毒" (LC50>96小时1000毫克/升),两种表面活性剂在28天内显示生物降解率>60%.

结论:

皮产生的表面活性剂,特别是SOPIL,是有效的,对环境无害的替代品,用于清理漏油.
使用生物相容和可生物降解的表面活性剂与可持续环境管理的绿色化学原则保持一致.
这些发现凸显了将农业废弃物价值化为生态应用的高价值产品的潜力.

关键词:

可生物降解,可生物降解.分散剂的有效性分散剂的有效性.油污泄漏油污泄漏油污泄漏油污泄漏油污泄漏油污泄漏油污泄漏油污泄漏油污泄漏油污泄漏油污泄漏油污泄漏油污泄漏油污泄漏油一个子皮子皮.表面活性剂是一种表面活性剂.毒性的毒性毒性的毒性

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