颗粒填充的聚合物复合材料的老化性能的多尺度模型
Congli Fang1, Huizhen Wang1, Yujiao Zhang1
1Smart Materials and Advanced Structure Laboratory, School of Mechanical Engineering and Mechanics, Ningbo University, Ningbo 315211, China.
Polymers
|August 12, 2023
概括
一个新的多尺度模型准确地预测了颗粒填充聚合物复合材料 (PFPC) 在热和氧化下的老化. 该模型将微观的聚合物变化与宏观性质相结合,用于可靠的性能预测.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物科学 聚合物科学
- 复合材料 复合材料 复合材料
背景情况:
- 颗粒填充的聚合物复合材料 (PFPC) 在热氧化老化下容易降解.
- 预测PFPC的长期性能需要了解复杂的衰老机制.
研究的目的:
- 开发一种新的多尺度模型来预测PFPC的老化性能.
- 通过实验数据验证模型的可靠性.
主要方法:
- 进行了高温加速老化试验.
- 显微镜分析的重点是聚合物矩阵交联密度.
- 宏观分析检查了弹性模量和潮湿应变关系.
- 构建了一个多尺度模型,整合了微观和宏观的发现.
主要成果:
- 交联密度的演变与聚合物氧化动力学有关.
- 通过聚合物物理学,建立了交联密度和弹性模量之间的相关性.
- 分析了宏观行为,包括潮湿应变,与弹性模量相关.
- 开发的多尺度模型在预测PFPC老化方面表现出很高的准确性.
结论:
- 这种新型的多尺度模型有效地预测了PFPC在热氧化条件下的老化性能.
- 该模型的预测与实验结果一致,证实了它的可靠性.
- 这种方法为评估聚合物复合材料的耐用性提供了一个强大的工具.
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