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编辑:分子打印聚合物的进步

Michał Cegłowski1

  • 1Faculty of Chemistry, Adam Mickiewicz University, Uniwersytetu Poznańskiego 8, 61-614 Poznan, Poland.

Polymers
|August 12, 2023
PubMed
概括

分子印记聚合物 (MIP) 为提取和分离提供独特的识别特性. 它们的实用性正在扩展到新的领域,如传感器构造和药物输送系统.

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Acyclic diene metathesis polymerization or ADMET polymerization involves cross-metathesis of terminal dienes, such as 1,8-nonadiene, to give linear unsaturated polymer and ethylene. As ADMET is a reversible process, the formed ethylene gas must be removed from the reaction mixture to complete the polymerization process.
Similar to cross-metathesis, ADMET also involves the formation of metallacyclobutane intermediate by [2+2] cycloaddition of one of the double bonds of a terminal diene with...