了解粒度边界对环氧/石墨烯复合材料机械性能的影响
Qiuyue Ding1,2, Ning Ding1,2, Xiangfeng Chen1
1Engineering Research Center of Failure Analysis and Safety Assessment, Shandong Analysis and Test Center, Qilu University of Technology (Shandong Academy of Sciences), Jinan 250014, China.
Polymers
|August 12, 2023
概括
石墨烯中的粒度边界 (GBs) 显著影响环氧复合材料的机械性能. 模拟显示GBs可以加强或削弱复合材料,影响拉伸/压缩行为和玻璃过渡温度.
科学领域:
- 材料科学 材料科学 材料科学
- 计算材料科学科学 计算材料科学
- 聚合物科学 聚合物科学
背景情况:
- 环氧/石墨烯复合材料是具有可调节性质的先进材料.
- 石墨烯增强剂中的粒度边界 (GB) 可以影响复合材料的性能.
- 对GB效应的原子学理解对于材料设计至关重要.
研究的目的:
- 研究石墨烯中各种粒度边界 (GB) 模型对环氧复合材料的机械性能的影响.
- 阐明所观察到的属性变化背后的原子化机制.
- 为设计具有缺陷石墨烯增强的环氧基复合材料提供见解.
主要方法:
- 使用了分子动力学 (MD) 模拟.
- 为石墨烯建造了十种不同的GB模型.
- 模拟分析了拉伸/压缩行为,玻璃过渡温度 (Tg) 和复合材料配置.
主要成果:
- GBs显著影响了拉伸/压缩行为,Tg,以及环氧/石墨烯复合材料的配置.
- 拉力承压强度因GB和负载方向而异 (增强或减弱).
- 压力承受强度超过拉力承受强度;Tg提高了最佳的界面相互作用和纹屈曲.
结论:
- GBs引入复杂的多因素合效应 (增强强度,界面能量,屈曲度) 对复合材料的机械性能.
- 这些因素的平衡决定了各种拉力承压强度的结果.
- 了解原子级别的GB机制是开发具有工程石墨烯缺陷的优质环氧复合材料的关键.
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