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相关概念视频

Molecular and Ionic Solids02:54

Molecular and Ionic Solids

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Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
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A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
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Ionic Bonding and Electron Transfer02:48

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Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions. 
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Substances that undergo either a physical or a chemical change in solution to yield ions that can conduct electricity are called electrolytes. If a substance yields ions in solution, that is, if the compound undergoes 100% dissociation, then the substance is a strong electrolyte. Complete dissociation is indicated by a single forward arrow. For example, water-soluble ionic compounds like sodium chloride dissociate into sodium cations and chloride anions in aqueous solution.
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Metallic Solids

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Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
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Ion exchange chromatography separates charged molecules from a solution by reversibly exchanging them with mobile, or 'active', ions associated with the oppositely charged stationary phase. This method can be used to separate ions, soften and deionize water, and purify solutions. The polymers comprising the ion-exchange column are high-molecular-weight and chemically stable polymers, crosslinked to be porous and essentially insoluble. They are also functionalized with either acidic or...
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Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
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关于用于固态金属电池的聚合物电解质的思考

Ziyu Song1, Fangfang Chen2, Maria Martinez-Ibañez3

  • 1Key Laboratory of Material Chemistry for Energy Conversion and Storage (Ministry of Education), School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Luoyu Road 1037, 430074, Wuhan, China.

Nature communications
|August 12, 2023
PubMed
概括

固体聚合物电解质 (SPEs) 正在使固态金属电池 (SSLMBs) 重生,这是由于当前离子电池 (LIBs) 的局限性. 研究重点是改进SPEs以获得更安全,更高能量的SSLMB.

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科学领域:

  • 材料科学 材料科学 材料科学
  • 电化学 电化学 电化学
  • 储能 储能 储能 储能 储能 储能

背景情况:

  • 离子电池 (LIB) 面临能源和安全限制.
  • 固态金属电池 (SSLMB) 之前由于安全问题而被放弃.
  • 对SSLMBs的重新兴趣是由LIB技术的局限性驱动的.

研究的目的:

  • 为SSLMBs提供固体聚合物电解质 (SPEs) 的历史视角.
  • 分析SPE特征,包括合和脱的概念.
  • 确定挑战,并为SSLMB中的SPEs提出改进建议.

主要方法:

  • 综述SPEs的历史发展情况.
  • 基于合/解合概念的SPE属性的分析.
  • 检查SPE改善的潜在补救措施.

主要成果:

  • 对于SSLMBs的复兴,SPEs至关重要.
  • 了解合和解合的SPE行为是关键.
  • 为了实现理想的SSLMB性能,需要改进SPEs.

结论:

  • 在推进SSLMB技术方面,SPE是核心的.
  • 需要对SPE进行进一步的研究,以克服目前的局限性.
  • 创新的SPE材料对于下一代高能电池至关重要.