基于Fe和Co的双金属催化剂支持Al支柱间层粘土:SCR-CH的制备,反应性和机制4
Shuying Ning1, Shasha Huang1, Honghai Yang1
1School of Environmental Science and Engineering, Donghua University, Shanghai 201620, China.
这项研究开发了一种新的铁双金属催化剂 (Fe-Co/Al-PILC),用于氧化的甲选择性催化还原 (SCR). 催化剂实现了高的N2选择性和NO转化,即使存在水和二氧化硫.
科学领域:
- 材料科学 材料科学 材料科学
- 催化剂是一种催化剂.
- 环境化学环境化学
背景情况:
- 使用甲作为减少剂的氧化 (NOx) 的选择性催化降解 (SCR) 是一项有前途的排放控制技术.
- 开发高效稳定的催化剂,能够承受恶劣的反应条件,如水和二氧化硫的存在,仍然是一个挑战.
研究的目的:
- 准备和评估一种新的双金属催化剂Fe-Co/Al-PILC,用于以甲为基础的NOx的SCR.
- 研究铁和加载对催化剂性能和稳定性的影响.
- 阐明Fe-Co/Al-PILC催化剂的活性位点和反应机制.
主要方法:
- 阿尔柱状中间层粘土 (Al-PILC) 支是由蒙莫里隆尼特粘土通过浸制备的.
- 和铁被顺序加载到Al-PILC支上,以创建双金属催化剂 (Fe-Co/Al-PILC).
- 在固定床反应堆中评估了催化性能,并使用各种技术进行了催化剂表征,包括in situ DRIFTS.
主要成果:
- 0.27Fe-Co/Al-PILC催化剂在10%的H2O的情况下显示出100%的N2选择性和超过63%的NO转化.
- 添加铁显著提高了催化剂对水和二氧化硫的抗性.
- 鉴定发现了易斯和布伦斯特德酸位共存,其中易斯酸位占主导地位,并增强了甲激活.
- 铁促进了孤立的CO2+和COO物种的形成,而孤立的Fe3+颗粒改善了CH4-SCR性能.
结论:
- Fe-Co/Al-PILC催化剂对NOx的甲SCR非常有效,具有出色的活性和稳定性.
- 易斯酸位点和特定的Fe/Co物种在催化机制中起着至关重要的作用.
- 拟议的反应机制涉及酸盐和甲作为活性中间体.
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