用固体-气体接口方法合成的丰富g-C3-N4+的进化活动
Radha Rajendramani1, Krateeka Madan1, Mohammed Sadik Nalakath Kallingal2
1Department of Chemistry and DST Solar Energy Harnessing Centre (DSEHC), Indian Institute of Technology Madras, Chennai 600036, India.
富含的石墨碳化物 (g-C3N4) 板被合成用于高效的太阳能气生产. 经过氨处理的g-C3N4衍生物显示出对水分裂的显著增强的光催化活性.
科学领域:
- 材料科学 材料科学 材料科学
- 光催化作用的光催化
- 可再生能源可再生能源是可再生能源.
背景情况:
- 使用无金属光催化剂有效地将太阳能转化为,对于可持续能源至关重要.
- 开发具有增强性能的富含的石墨碳化物 (g-C3N4) 衍生物仍然是一个挑战.
研究的目的:
- 使用固体气体接口方法合成富含的g-C3N4衍生物.
- 为了研究兴奋剂对进化的光催化性能的影响.
主要方法:
- 通过固体气体接口方法,在氨流下合成纯的g-C3N4 (CN),g-C3N4+ (CN-NH3),在流下合成纯的g-C3N4+ (CN-N2).
- 材料属性的表征,包括表面导电性,光学吸收率和电子供体密度.
- 光电化学进化 (HER) 测量和光催化水分裂试验.
- 密度函数理论 (DFT) 计算以了解带间隙修改.
主要成果:
- 该CN-NH3样本表现出优越的表面导电性,广泛的可见光吸收,减少的电荷重组,以及高的电子捐赠密度.
- CN-NH3的光电流密度为2.06μA cm-2,是纯CN (0.85μA cm-2) 的2.5倍.
- CN-NH3 显示了增强的光催化水分裂,在没有共催化剂的情况下产生 634 μmol g-1 H2 和 1163 μmol g-1 H2 与 Pt.
- DFT的计算表明,增加的N-doping通过增加部分π占用来逐渐减少带间隙,稳定传导带最小值.
结论:
- 固体气体接口方法成功地产生了富含的g-C3N4板,具有增强的光催化活性.
- 氨处理显著提高了g-C3N4的性能,用于太阳能进化,由于电子和光学性能得到了改进.
- 理论建模支持实验结果,解释了带间隔调机制通过杂剂.
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