关于页岩油-CO2 - 水的可混合性,竞争性吸附和多相流动行为的孔尺度研究
Han Wang1, Jianchao Cai1, Yuliang Su2,3
1National Key Laboratory of Petroleum Resources and Engineering, China University of Petroleum, Beijing 102249, P. R. China.
Langmuir : the ACS journal of surfaces and colloids
|August 15, 2023
概括
页岩中存在的水阻碍了地质二氧化碳的封存和二氧化碳气过程中的石油回收,减少了二氧化碳的储存和由于毛细管力而导致的油位移. 油-二氧化碳的混合性也会影响流动行为和相对透性.
科学领域:
- 石油工程是石油工程中的一个.
- 地质碳封存地质碳封存
- 纳米孔径媒体流
背景情况:
- 石油-水双相流体在页岩纳米孔隙介质中很常见,这是由于裂变流体和初级水.
- 水相在CO2 huff-n-puff过程中显著影响页岩油回收和地质碳捕获效率.
- 石油-二氧化碳的混合性影响了页岩中的双相流动行为和可湿性.
研究的目的:
- 通过使用改进的格子博尔兹曼法,研究水相对页岩中的二氧化碳的影响.
- 分析油-二氧化碳混合性如何影响油-水流动行为和相对透性.
- 为了量化地质二氧化碳储存质量和考虑到水和度的油水相对透性.
主要方法:
- 开发了一种改进的多组件,多相格子博尔茨曼法.
- 嵌入式油-CO2竞争性吸附和混合效应对水的可湿性.
- 利用分子动力学模拟来研究油-CO2混合性对相对透性的影响.
主要成果:
- 通过Jamin效应和毛细血管阻力,水的存在阻碍了CO2扩散,并增加了剩余的油.
- 增加的水和度加剧了毛细血管力,减少了二氧化碳储存质量.
- 油-二氧化碳混合性降低了油的相对透性,并且随着油度的下降,增加了水的相对透性.
结论:
- 在二氧化碳注入过程中,水相显著阻碍了页岩中的二氧化碳扩散和石油回收.
- 开发的格子博尔茨曼模型准确地预测了二氧化碳的储存和油水流动行为.
- 这些发现对于优化页岩油回收和地质碳捕获策略至关重要.
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