铁磁GdS2,GdSe2和Janus GdSSe单层的可调节的电特性和多相性
Zhihao Gao1, Yuehao Yin2, Yuwan Wang1
1State Key Laboratory of Solidification Processing, Center for Advanced Lubrication and Seal Materials, School of Material Science and Engineering, Northwestern Polytechnical University, 127 YouYi Western Road, Xi'an, Shaanxi 710072, China. xlfan@nwpu.edu.cn.
Physical chemistry chemical physics : PCCP
|August 16, 2023
概括
新型二维 (2D) 铁磁材料,GdS2,GdSe2和Janus GdSSe单层,表现出双极磁性半导体和铁弹性性能. 这些材料对先进的纳米级自旋电子设备具有前景.
科学领域:
- 材料科学 材料科学 材料科学
- 凝聚物质物理学 凝聚物质物理学
- 纳米技术纳米技术
背景情况:
- 螺旋电子设备的集成需要具有不同电性质的新型二维 (2D) 铁磁材料.
- 探索新的二维材料对于推进自旋电子和纳米电子技术至关重要.
研究的目的:
- 为了研究三种新的铁磁单层的特性:GdS2,GdSe2和Janus GdSSe.
- 评估它们在自旋电子设备中的应用潜力.
主要方法:
- 使用第一原理计算来研究结构性,磁性和电子性质.
- 评估了拟议的单层的稳定性和实验可行性.
主要成果:
- GdS2,GdSe2和Janus GdSSe被确定为具有显著铁弹性 (73.2%可逆应变) 的双极磁性半导体.
- 这些材料具有很大的磁矩 (~8μB f.u.−1) 和相当大的旋转翻转能量差距,适用于旋转过器和旋转.
- 对于GdS2和GdSe2的稳定方格格子表现出高基里温度 (分别为648K和312K) 和无旋隙半导体特性.
- 由于旋转轨道合和磁交换相互作用,观察到内在山谷极化.
结论:
- 新发现的GdS2,GdSe2和Janus GdSSe单层是下一代多功能旋转器件的有希望的候选者.
- 它们的磁性,电子性和机械性质的独特组合使它们非常适合纳米级应用.
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