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相关概念视频

Formation of Complex Ions03:45

Formation of Complex Ions

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A type of Lewis acid-base chemistry involves the formation of a complex ion (or a coordination complex) comprising a central atom, typically a transition metal cation, surrounded by ions or molecules called ligands. These ligands can be neutral molecules like H2O or NH3, or ions such as CN− or OH−. Often, the ligands act as Lewis bases, donating a pair of electrons to the central atom. These types of Lewis acid-base reactions are examples of a broad subdiscipline called coordination...
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A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
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Complexation Equilibria: Factors Influencing Stability of Complexes01:09

Complexation Equilibria: Factors Influencing Stability of Complexes

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In complexation reactions, metal cations are the electron pair acceptors, and the ligands are the electron pair donors. The stability of the metal complexes depends primarily on the complexing ability of the central metal ion and the nature of the ligands. Generally, the complexing ability of the metal ion depends on the size and charge of the ion. As the metal ion size increases, the stability of the metal complexes decreases, provided that the valency of the metal ion and the ligands remain...
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The Supercomplexes in the Crista Membrane01:41

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The mitochondrial cristae membrane is the primary site for the oxidative phosphorylation (OXPHOS) process of energy conversion mediated through respiratory complexes I to V. These complexes have been widely studied for decades, and it has been proven that they form supramolecular structures called respiratory supercomplexes (SC). These higher-order complexes may be crucial in maintaining the biochemical structure and improving the physiological activity of the individual complexes while...
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Ionic Bonding and Electron Transfer02:48

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Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions. 
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Metal ions can be separated from one another by complexation with organic ligands–the chelating agent– to form uncharged chelates. Here, the chelating agent must contain hydrophobic groups and behave as a weak acid, losing a proton to bind with the metal. Since most organic ligands used in this process are insoluble or undergo oxidation in the aqueous phase, the chelating agent is initially added to the organic phase and extracted into the aqueous phase. The metal-ligand complex is...
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高性能硫电池通过分子复合

Peiyu Wang1, Nikolaos Kateris2, Baiheng Li1

  • 1Thayer School of Engineering, Dartmouth College, Hanover, New Hampshire 03755, United States.

Journal of the American Chemical Society
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概括

研究人员使用二复合物开发了一种新型的液体硫阴极. 这一突破提高了硫电池在广泛温度范围内的稳定性和性能, 克服了关键的限制.

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科学领域:

  • 电化学
  • 材料科学
  • 能量储存

背景情况:

  • 硫电池在理论上具有很高的特定能量,但由于聚硫化物沉和体积变化,其长期稳定性不佳.
  • 现有的硫电池设计面临着不可逆转的变化和有限的操作温度范围.

研究的目的:

  • 设计和开发用于硫电池的稳定液硫电极.
  • 克服聚硫化物穿和硫电池阴极体积扩张的局限性.
  • 在广泛的温度范围内实现高特异性和循环稳定性.

主要方法:

  • 在有机溶剂中溶解的二复合物的开发,以形成液硫电极.
  • 利用合光谱和密度功能理论 (DFT) 研究来了解分子设计和反应机制.
  • 电化学测试以评估特定容量,循环稳定性和低温性能.

主要成果:

  • 在0.2°C下达到1425mAh-1的高特异性容量,在0.5°C下400次循环后保持80%的容量.
  • 在低温下表现出卓越的性能,容量在-40°C时超过400 mAh,在-60°C时超过200 mAh.
  • 液硫电极有效地结合和储存放电产品,防止沉并实现可逆电化学转换.

结论:

  • 基于硫酸盐复合物的新型液硫电极显著提高了硫电池的稳定性和性能.
  • 这种方法为聚硫化物转运和硫阴极体积变化的挑战提供了可行的解决方案.
  • 开发的技术为设计先进电池的高性能,宽温度范围的硫电极开辟了新的途径.