多刺激室温光聚合物对光和酸敏感,循环与能量转移
Yuqi Yang1, Aisen Li1, Yujie Yang1
1Institute of Molecular Aggregation Science, Tianjin University, Tianjin, 300072, China.
Angewandte Chemie (International ed. in English)
|August 17, 2023
概括
新的动态色调共聚物表现出刺激响应的室温光 (RTP). 这些材料在聚烯胺中包含烯和螺旋 (SP),在光或酸刺激下,将排放从绿色转变为色,从而使新的信息保护应用成为可能.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 光物理学的光学物理学
背景情况:
- 响应刺激的材料提供了动态的功能.
- 室温光 (RTP) 允许持续的光发射.
- 控制排放颜色对于高级应用至关重要.
研究的目的:
- 开发新的动态色调无形共聚合物.
- 为了研究刺激响应的RTP行为.
- 探索信息保护和信息传递中的应用.
主要方法:
- 在聚烯胺基质中加入纳夫他林 (能量供体) 和螺旋 (SP,能量接受体).
- 合成具有良好的稳定性和可加工性的无形共聚物.
- 研究纳夫他林和SP之间的能量传递机制.
主要成果:
- 制备光亮,动态的可调色色彩的无形共聚合物.
- 实现后照排放,可根据照片或酸性刺激从绿色调整到色.
- 证明了SP和可调节发光的能量转移的多重责任.
- 在动态可控制的信息保护和传输系统中成功应用共聚物.
结论:
- 合成的共聚合物表现出优异的刺激响应RTP特性.
- 动态色调性归因于能量转移和SP的多重责任.
- 这些材料在安全信息管理中具有先进应用的巨大潜力.
相关概念视频
Photoluminescence: Applications
430
Photoluminescence offers a wide range of applications due to its inherent sensitivity and selectivity. This technique allows for both direct and indirect analyses of the analyte. Direct quantitative analysis is possible when the analyte exhibits a favorable quantum yield for fluorescence or phosphorescence. However, an indirect analysis may be feasible if the analyte is not fluorescent or phosphorescent, or if the quantum yield is unfavorable. Indirect methods include reacting the analyte with...
430
Variables Affecting Phosphorescence and Fluorescence
532
Fluorescence and phosphorescence are essential phenomena in fields like analytical chemistry, biological imaging, and materials science, where they detect molecular properties and visualize cellular structures. Understanding the variables that influence these luminescent behaviors is crucial for maximizing accuracy and efficiency in their applications. These variables can broadly be grouped into chemical structure, solvent properties, and external conditions, each playing a distinct role in...
532
Photoluminescence: Fluorescence and Phosphorescence
2.1K
Photoluminescence is a process where a molecule absorbs light energy and re-emits it in the form of light. This phenomenon occurs when a substance absorbs photons, promoting its electrons to higher energy level excited states, followed by a relaxation process in which the electrons return to their original ground state energy levels and emit light. Photoluminescence is widely observed in various materials, including semiconductors, and organic and inorganic compounds.
A pair of electrons in a...
A pair of electrons in a...
2.1K
Fluorescence and Phosphorescence: Instrumentation
643
Fluorometers and spectrofluorometers are two types of instruments used for measuring molecular fluorescence. These instruments differ in how they select excitation and emission wavelengths and the type of light sources they utilize. Fluorometers use absorption interference filters to choose excitation and emission wavelengths. The excitation source in a fluorometer is typically a low-pressure mercury vapor lamp that emits intense lines distributed throughout the ultraviolet and visible regions.
643


