通过能量转移在Mg2和GeO中实现Yb3+与可见光反应的发光
Yongcheng Huo1, Hao Cai1, Yuhe Shao1
1The Beijing Municipal Key Laboratory of New Energy Materials and Technologies, School of Materials Sciences and Engineering, University of Science and Technology Beijing, Beijing 100083, China.
Inorganic chemistry
|August 18, 2023
概括
研究人员开发了一种新的,Mg2GeO4:Cr3+,Yb3+,可以吸收蓝光并发射近红外 (NIR) 光. 这种材料对具有成本效益的红外光源和温度传感应用具有前景.
科学领域:
- 材料科学 材料科学 材料科学
- 频谱学是一种光谱学.
- 固态化学 固态化学
背景情况:
- 在生物成像,食品分析和温度传感方面,对红外光谱应用的需求日益增长.
- 需要光器,将来自LED的蓝光转化为长波长红外发光,以实现成本效益的系统.
研究的目的:
- 研究Cr3+-Yb3+在Mg2GeO4中的能量转移,用于可见光转化为红外光.
- 为了探索Mg2GeO4:Cr3+,Yb3+作为温度传感器的潜力.
主要方法:
- 用Cr3+和Yb3+添加Mg2GeO4的合成和表征.
- 分析局部结构和Yb3+离子占用.
- 研究从Cr3+到Yb3+的能量转移机制.
- 评估发光特性和温度依赖的辐射强度.
主要成果:
- 在Mg2GeO4.4中通过Cr3+-Yb3+能量转移实现了可见光响应的Yb3+发光.
- 观察到强烈的近红外 (NIR) 发光,在974nm达到峰值.
- 证明了Yb3+离子的优先占用,并阐明了能量转移过程.
- 证实了温度依赖的排放强度变化.
结论:
- Mg2GeO4:Cr3+,Yb3+有效地将可见光转化为NIR发光.
- 由于温度敏感的排放,该材料具有作为温度计的应用潜力.
- 这项工作有助于开发用于光谱和传感的先进.
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