在剪切和压缩中模拟聚合的2D悬浮:从流体层到辅助性接口?
Alexandra Alicke1, Laura Stricker1, Jan Vermant1
1Department of Materials, ETH Zurich, Vladimir-Prelog-Weg 5, Zurich 8093, Switzerland.
Journal of colloid and interface science
|August 19, 2023
概括
带有粒子的接口在压缩和剪切下表现出明显的机械反应. 它们的压缩模块取决于空隙分数,而剪切模块与总分数维度相关,揭示了复杂的微观结构变化.
科学领域:
- 材料科学 材料科学 材料科学
- 软物质物理学 软物质物理学
- 体科学 体科学 体科学
背景情况:
- 带有粒子的接口对于多相系统的稳定性至关重要.
- 了解它们在变形下的机械性能是有限的.
- 伴随机械反应的微观结构变化需要进一步研究.
研究的目的:
- 在聚合的2D颗粒悬浮液中研究界面的质模块.
- 在剪切和压缩下与微观结构演变相关联的质模块.
- 探索这些异质网络的辅助性行为.
主要方法:
- 在简单的剪切流 (双墙环几何) 和同otropic压缩 (辐射) 中进行了接口的风学实验.
- 多样化的表面覆盖和保持干净的动力学条件.
- 在变形过程中监测微结构演变.
主要成果:
- 压缩模块以非单调的方式增加,空隙分数因聚合物密集和空隙关闭而减少.
- 剪切模块随着总体骨干的碎形维度的增加而单调地增加.
- 在中间覆盖处观察到2D辅助性行为,表明对变形的弹性.
结论:
- 界面类风湿学与粒子网络中的微观结构变化密切相关.
- 截然不同的变形机制控制着压力和剪切模块.
- 这些接口的辅助性质对颗粒涂层滴滴和泡稳定性有影响.
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