一种具有四个疏水分支和四个离子中心的离子液体的合成和脱硫机制
Qian Qu1, Huan Li2, Shuman Li2
1School of Chemistry & Environmental Engineering, Yangtze University, Jingzhou, 434023, PR China.
Chemosphere
|August 20, 2023
概括
两种新的离子液体PPBD和PPBH在低温下有效地分解油水乳液. PPBH实现了96.34%的脱效率,显示出出色的耐盐性和工业应用的潜力.
科学领域:
- 化学工程是化学工程的重要组成部分.
- 环境科学 环境科学
背景情况:
- 稳定的油水乳液带来了重大的环境和工业挑战.
- 有效的脱硫对于石油回收和废水处理至关重要.
研究的目的:
- 合成和评估新型离子液体 (PPBD和PPPH) 作为石油水乳液的高效脱乳剂.
- 为了研究不同条件下的脱性能,并与商业脱剂进行比较.
主要方法:
- 具有四个疏水分支和四个离子中心的离子液体的合成.
- 使用FT-IR和1H NMR光谱学进行表征.
- 在不同温度,度,油水比,盐度和pH下测试脱效率.
主要成果:
- 在120分钟内,PPBH在40°C的E30乳液中实现了96.34%的脱乳效率.
- 在40°C的E30乳液中,PPBD在360分钟内实现了95.23%的效率.
- PPBH在E70乳液中表现出100%的效率和出色的耐盐性,优于商业脱乳剂.
结论:
- 合成的离子液体PPBD和PPPH是油水乳液的有效低温脱乳剂.
- PPBH表现出卓越的性能,高盐耐受性,以及在油水分离中工业应用的潜力.
相关概念视频
Intermolecular Forces
58.7K
Atoms and molecules interact through bonds (or forces): intramolecular and intermolecular. The forces are electrostatic as they arise from interactions (attractive or repulsive) between charged species (permanent, partial, or temporary charges) and exist with varying strengths between ions, polar, nonpolar, and neutral molecules. The different types of intermolecular forces are ion–dipole, dipole–dipole, hydrogen bonds, and dispersion; among these, dipole–dipole, hydrogen...
58.7K
Entropy and Solvation
7.1K
The process of surrounding a solute with solvent is called solvation. It involves evenly distributing the solute within the solvent. The rule of thumb for determining a solvent for a given compound is that like dissolves like. A good solvent has molecular characteristics similar to those of the compound to be dissolved. For example, polar solutions dissolve polar solutes, and apolar solvents dissolve apolar solutes. A polar solvent is a solvent that has a high dielectric constant (ϵ...
7.1K
Intermolecular Forces in Solutions
34.0K
The formation of a solution is an example of a spontaneous process, a process that occurs under specified conditions without energy from some external source.
When the strengths of the intermolecular forces of attraction between solute and solvent species in a solution are no different than those present in the separated components, the solution is formed with no accompanying energy change. Such a solution is called an ideal solution. A mixture of ideal gases (or gases such as helium and argon,...
When the strengths of the intermolecular forces of attraction between solute and solvent species in a solution are no different than those present in the separated components, the solution is formed with no accompanying energy change. Such a solution is called an ideal solution. A mixture of ideal gases (or gases such as helium and argon,...
34.0K
Intermolecular Forces and Physical Properties
20.9K
20.9K
Solubility
17.5K
Solution, Solubility, and Solubility Equilibrium
A solution is a homogeneous mixture composed of a solvent, the major component, and a solute, the minor component. The physical state of a solution—solid, liquid, or gas—is typically the same as that of the solvent. Solute concentrations are often described with qualitative terms such as dilute (of relatively low concentration) and concentrated (of relatively high concentration).
In a solution, the solute particles (molecules,...
A solution is a homogeneous mixture composed of a solvent, the major component, and a solute, the minor component. The physical state of a solution—solid, liquid, or gas—is typically the same as that of the solvent. Solute concentrations are often described with qualitative terms such as dilute (of relatively low concentration) and concentrated (of relatively high concentration).
In a solution, the solute particles (molecules,...
17.5K
Colloids
17.6K
Children at play often make suspensions such as mixtures of mud and water, flour and water, or a suspension of solid pigments in water known as tempera paint. These suspensions are heterogeneous mixtures composed of relatively large particles that are visible to the naked eye or can be seen with a magnifying glass. They are cloudy, and the suspended particles settle out after mixing. On the other hand, a solution is a homogeneous mixture in which no settling occurs and in which the dissolved...
17.6K


