在铁电VS2/Ga2O3范德瓦尔斯异构结构中,依赖于静电门的多频段对齐
Yunlai Zhu1, Zihan Qu1, Xiaoteng Wang1
1School of Integrated Circuits, Anhui University, Hefei, Anhui, 230601, China. daiyuehua2013@163.com.
Physical chemistry chemical physics : PCCP
|August 22, 2023
概括
使用VS2/Ga2O3的二维 (2D) 范德瓦尔斯异构结构显示可调节的电子特性. 极化逆转改变了带的对齐,使其在铁电记忆和多功能设备中的潜在应用成为可能.
科学领域:
- 材料科学 材料科学 材料科学
- 凝聚物质物理学 凝聚物质物理学
- 纳米技术纳米技术
背景情况:
- 具有内在铁电的二维 (2D) 范德瓦尔斯 (vdW) 异构结构对于先进的记忆器件至关重要.
- 铁电器中的可逆极化使得可调节的带对齐能够实现新的功能.
研究的目的:
- 研究2D VS2/Ga2O3 vdW异构结构的结构和电子特性.
- 探索极化和外部电场对带对齐的影响.
- 确定铁电记忆器和多功能电子设备的潜在应用.
主要方法:
- 使用密度函数理论 (DFT) 的第一原则计算.
- 将范德瓦尔斯 (vdW) 校正纳入 DFT-D2 方法.
- 在不同极化状态下分析波段结构和波段对齐.
主要成果:
- 2D Ga2O3的极化会在异构结构中诱导金属到半导体的过渡.
- 在特定电场下,VS2/Ga2O3异构结构表现出I型和II型频段对齐.
- 外部电场可以在VS2/Ga2O3.3中切换频段对齐类型 (例如,II型到I/III型).
结论:
- 该研究展示了一种控制2D VS2/Ga2O3 vdW异构结构中带对齐的方法.
- 这些异构结构显示出铁电记忆应用的前景.
- 可调节带对齐为依赖于静电门的多功能设备提供了途径.
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