在电子辐射下通过分子氧和E'中心形成探测密集的二氧化玻璃结构
N Ollier1, I Reghioua2, O Cavani2
1Laboratoire des Solides Irradiés Ecole Polytechnique, CNRS, CEA\DRF\IRAMIS, Institut Polytechnique de Paris, 91128, Palaiseau Cedex, France. nadege.ollier@polytechnique.edu.
Scientific reports
|August 22, 2023
概括
对密集的二氧化进行电子辐射,揭示了对其金属状相的洞察力. 高剂量辐射形成间歇性分子氧 (O2),它对二氧化网络结构和空隙大小敏感.
科学领域:
- 材料科学 材料科学 材料科学
- 固态物理 固态物理
- 陶制品 在陶方面.
背景情况:
- 密集的二氧化具有独特的结构特性.
- 中的甲化可以改变其缺陷结构.
- 了解缺陷形成对于材料应用至关重要.
研究的目的:
- 调查类似甲的二氧化的结构.
- 检查E'点缺陷和间歇性分子氧 (O2) 的形成.
- 关联结构变化与辐射诱导的缺陷.
主要方法:
- 2.5 MeV电子辐射的二氧化.
- 高剂量 (11 GGy) 和随后较低剂量的辐射.
- 阴极光发光 (CL) 光谱法用于分析O2排放.
主要成果:
- 高剂量的辐射产生了一个类似于甲的阶段,其中含有丰富的间歇性O2.
- 间歇性O2形成取决于网中的四面体间空隙大小.
- 氧2排放特征表明,在甲基阶段的空隙配置类似于非密集的二氧化.
- 在3个成员的Si-O环,E'-中心和增加的密度之间发现了强烈的相关性.
结论:
- 这项研究阐明了空隙大小在密集的二氧化中O2形成中的作用.
- 辐射诱导的缺陷,E'中心和O2,与结构变化有关,比如3个成员环的形成.
- 结果提供了关于在辐射下密集的结构演变的见解.
相关概念视频
Ionic Bonding and Electron Transfer
Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions.
Lewis Structures of Molecular Compounds and Polyatomic Ions
To draw Lewis structures for complicated molecules and molecular ions, it is helpful to follow a step-by-step procedure as outlined:
Ionic Crystal Structures
Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
Atomic Emission Spectroscopy: Overview
Atomic emission spectroscopy (AES) is an analytical technique used to determine the elemental composition of a sample by analyzing the light emitted from excited atoms. In AES, atoms in a sample are excited to higher energy levels by thermal energy from high-temperature sources, such as plasma, arcs, or sparks. When these excited atoms return to lower energy states, they emit light at specific wavelengths characteristic of each element. The resulting atomic emission spectrum, which consists of...
The Electrical Double Layer
In the region where two bulk phases meet, an intricate electric charge distribution arises due to charge transfer, ion adsorption, molecular orientation, and charge distortion. This complex distribution is commonly referred to as the electrical double layer.When a solid electrode interfaces with ions in an electrolyte solution, the speed of electron transfer dictates the rates of oxidation and reduction. The electrode acquires a charge through the escape of atoms into the solution as cations or...
Determination of Crystal Structures
In the late 1800s, the revelation that light extended beyond visible wavelengths led to the discovery of X-rays by Wilhelm Roentgen. Recognized as high-energy electromagnetic radiation with short wavelengths, X-rays prompted exploration into their interaction with crystals. Max von Laue proposed in 1912 that the periodic arrangement of atoms, ions, or molecules in crystals would cause them to diffract X-rays, a hypothesis confirmed through experiments with copper sulfate and zinc sulfide...


