在亚利桑那州马里科帕县测量挥发性有机化合物的来源分配
Luke Pramod1, Matthew P Fraser1
1School of Sustainable Engineering and the Built Environment, Arizona State University, Tempe, AZ, USA.
Journal of the Air & Waste Management Association (1995)
|August 23, 2023
概括
这项研究比较了马里科帕县挥发性有机化合物 (VOC) 的自上而下的和自下而上的模型. 生物源和天然气排放的差异表明,需要进一步调查以准确评估空气质量.
科学领域:
- 环境化学环境化学
- 大气科学 大气科学
- 空气质量建模空气质量模型
背景情况:
- 亚利桑那州马里科帕县现有的挥发性有机化合物 (VOC) 排放库存需要证实.
- 基于监管工程的库存通常使用"自下而上的"建模方法开发.
- 了解VOC来源对于评估热层臭氧的形成及其对公共健康的影响至关重要.
研究的目的:
- 独立证实马里科帕县空气质量部门 (MCAQD) 2020年臭氧前体的周期性排放清单.
- 为了比较"自上而下"的化学质量平衡 (CMB) 建模与"自下而上"的VOC清单方法.
- 为了确定VOC排放源贡献的差异,并指导未来的空气质量调查.
主要方法:
- 在马里科帕县测量环境VOC度的统计分析.
- 化学质量平衡 (CMB) 模型的应用,使用来自城JLG超级站的环境VOC数据.
- 使用了来自美国环保署的SPECIATE数据库的排放源资料.
- 通过各种源配置文件的试错,优化了CMB模型性能.
主要成果:
- 使用CMB模型生成的VOC排放源贡献估计.
- 将CMB衍生的"自上而下的"估计与现有的"自下而上的"监管库存进行比较.
- 确定了对生物源和天然气燃烧源的两种建模方法之间的差异.
结论:
- 该研究强调了特定来源的当前VOC排放清单中潜在的低估或不准确性.
- 建议对生物和天然气燃烧源进行进一步调查,以改进排放强度估计.
- 调查结果提供了关于VOC途径的宝贵见解,这些途径有助于马里科帕县的热层臭氧形成,有助于环境和健康评估.
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