由裂和内在缺陷产生的均分布的电流密度诱导的小型再生石墨颗粒的优异速率能力
Haoran Da1,2,3, Wenhao Fang1,2, Jiufu Zhu1,2
1CAS Key Laboratory of Green Process and Engineering, Beijing Key Laboratory of Ionic Liquids Clean Process, Institute of Process Engineering, Chinese Academy of Science, Beijing, 100190, China.
Small (Weinheim an der Bergstrasse, Germany)
|August 24, 2023
概括
经过再生的废旧石墨颗粒,涂上聚烯,增强快速充电的离子电池. 这种可持续的方法提高了电极性能和材料的再利用.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 可持续能源 可持续能源
背景情况:
- 使用过的电池是电极材料的宝贵来源,需要高效的再生技术.
- 小消耗石墨颗粒具有独特的结构缺陷,有利于高速充电和化动力学.
研究的目的:
- 开发一种再生技术,用于废弃的石墨颗粒,以提高快充电池的性能.
- 研究碳化聚烯涂层对回收石墨的电化学性能的影响.
主要方法:
- 选小的消耗石墨颗粒,并用碳化聚烯涂覆它们.
- 描述涂层石墨的结构和电化学特性.
- 评估电池性能,包括特定容量,速率能力和循环稳定性.
主要成果:
- 碳化聚烯涂层修复了结构缺陷,并促进了离子扩散.
- 再生石墨表现出优越的速率性能,在500个循环后在4C达到102.7 mAh g-1.
- 在快速充电期间观察到电流密度分布的增强均性.
结论:
- 用碳化聚烯烯涂覆使用过的石墨颗粒是高速电池应用的有效策略.
- 这种再生方法提供了一种可持续的方法,用于利用废物用于储能.
- 修改后的石墨可以有效地运输离子,并提高电池的寿命.
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