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聚乙烯) 作为离子和硫限制添加剂,用于硫电池
Rudy Martin Torres1, Amruth Bhargav1, Arumugam Manthiram1
1Materials Science & Engineering Program and Texas Materials Institute, The University of Texas at Austin, Austin, Texas 78721, United States.
ACS applied materials & interfaces
|August 24, 2023
概括
聚乙烯 (PvFc) 通过提高离子导电性和限制聚硫化物来提高硫 (Li-S) 电池的性能. 这种粘合剂添加剂提高了Li-S电池的速率能力和循环寿命.
科学领域:
- 电化学 电化学 电化学
- 材料科学 材料科学 材料科学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 硫 (Li-S) 电池提供高能量密度,但面临诸如聚硫化物穿和低导电性等挑战.
- 在Li-S阴极中的电流结合剂通常是惰性的,并不能有效地解决这些问题.
研究的目的:
- 研究聚乙烯 (PvFc) 作为一种结合剂添加剂,以提高Li-S电池的性能.
- 探索PvFc在增加离子导电性和减轻聚硫化物穿中的作用.
主要方法:
- 用PvFc粘合剂添加剂对Li-S阴极进行电化学测试.
- 离子导电性测量. 离子导电性测量.
- 在X射线光电子光谱学 (XPS) 分析.
主要成果:
- 添加PvFc显著增加了阴极离子导电性,提高了速率能力和循环寿命.
- 铁和Li+离子之间的π-离子相互作用改善了Li+的流动性.
- PvFc表现出硫化物限制作用,通过减轻聚硫化物溶解来减少容量衰减.
结论:
- 聚乙烯 (聚乙烯) 是Li-S电池的一个有前途的离子体,同时作为离子导电增强剂和聚硫化物清除剂.
- PvFc扩大了这种材料的实用性,超出了它在有机金属电池中的传统作用.
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