使用高灰煤污泥的化合物肥料的水热性合成和释放特性
Yanfei Tian1,2, Xianshu Dong3,4, Yuping Fan1
1Department of Mineral Processing Engineering, Taiyuan University of Technology, Taiyuan, 030024, Shanxi, China.
Environmental science and pollution research international
|August 24, 2023
概括
这项研究开发了一种新的方法,将高灰炭粘液转化为二氧化化合物肥料 (HASF). 这一过程优化了废物利用,并为改善土壤和施肥提供了潜力.
科学领域:
- 材料科学 材料科学 材料科学
- 环境科学 环境科学
- 农业科学 农业科学
背景情况:
- 高灰煤污泥带来了处置挑战和环境污染风险.
- 目前煤炭粘液的利用方法有限,特别是作为炉燃料.
- 需要可持续的解决方案来管理工业废物并支持肥料行业.
研究的目的:
- 开发一种新的方法来制备高灰炭粘土化合物肥料 (HASF).
- 优化利用高灰煤污泥作为一个有价值的工业废物产品.
- 评估HASF在土壤改善和肥料应用中的潜力.
主要方法:
- 一种CaO-KOH混合热水法用于HASF合成.
- 进行单因素实验以确定最佳反应条件 (温度,时间,KOH度).
- 材料表征涉及XRD,FTIR和SEM-EDS分析;通过溶解实验研究了释放.
主要成果:
- 在最佳条件下,HASF具有有效含量和符合市场要求的氧化和氧化总和.
- XRD和FTIR证实托伯莫里特和白石是HASF的主要矿物阶段.
- 溶解率遵循D4 > D1 ≈ D0,硫酸4mol/L的预激活增强了缓释特性.
结论:
- 开发的热水法有效地将高灰煤污泥转化为可行的化合物肥料 (HASF).
- HASF表现出有利于土壤改善和施肥的特性,显示出可持续废物管理的潜力.
- 用硫酸预激活会影响二氧化释放率,为农业应用提供可调节的特性.
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