精确的分子选乙烯从乙使用三基衍生子微孔碳膜
Khalid Hazazi1,2,3, Yingge Wang2, Bader Ghanem2
1Chemical Engineering Program, Physical Science and Engineering Division, King Abdullah University of Science and Technology, Thuwal, Saudi Arabia.
Nature materials
|August 24, 2023
概括
新的碳膜为能源密集型冷蒸提供了一个高度选择性和稳定的替代方案,用于将乙烯与乙分离. 膜技术的这一突破可以显著减少石化和天然气加工中的能源消耗.
科学领域:
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
- 分离技术 分离技术
背景情况:
- 用于乙烯/乙烯分离的冷蒸是耗能密集的.
- 现有的膜技术由于相似的分子大小 (乙烯:3.75 Å,乙:3.85 Å) 导致混合气体选择性较低.
- 石油化学分离需要高效和稳定的膜解决方案.
研究的目的:
- 开发先进的膜材料,以高效地分离乙烯/乙.
- 克服当前膜技术在混合气体选择性方面的局限性.
- 为了证明新型膜材料的工业适用性.
主要方法:
- 一种内在微性的三基梯级聚合物的热解,以创建碳膜.
- 制造具有精确分子选能力的亚微孔碳膜.
- 在工业条件下测试混合气体性能和长期稳定性 (10bar料压).
主要成果:
- 在乙烯/乙分离过程中实现了~100的无与伦比的混合气体选择性.
- 经过证明的塑化耐受性和长期连续稳定性30天.
- 开发了具有精确分子选特性的微孔碳膜.
结论:
- 开发的碳膜对现有的分离技术来说是一个显著的进步.
- 这些膜为乙烯/乙分离提供了一个有希望的,节能的替代方案.
- 该技术具有很大的潜力,可以在石化和天然气行业挑战分离.
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