模拟可交换液晶弹性体的粘性弹性和动态阴性顺序
Jiameng Zhao1,2, Fanlong Meng1,2,3
1CAS Key Laboratory of Theoretical Physics, Institute of Theoretical Physics, Chinese Academy of Sciences, Beijing 100190, China.
Physical review letters
|August 25, 2023
概括
这项研究模型可交换液晶弹性体 (XLCEs),可循环聚合物具有动态交叉链接. 该模型解释了它们独特的粘性弹性和动态阴性秩序,指导了未来的材料设计.
科学领域:
- 聚合物科学 聚合物科学
- 材料科学 材料科学 材料科学
- 类风病学 类风病学 类风病学
背景情况:
- 可交换液晶弹性体 (XLCE) 是具有动态交叉连接的可回收聚合物网络.
- 这些材料表现出复杂的行为,由于液晶性,网络弹性和链动态的相互作用.
研究的目的:
- 为XLCEs开发一个宏观连续模型,该模型包含微观动态交叉连接特征.
- 了解XLCEs中的粘性弹性和动态阴性秩序.
主要方法:
- 开发一个宏观连续模型.
- 将微观动态交叉连接特征纳入模型.
- 分析风湿反应,包括压力放松,应变坡道和爬行服从.
主要成果:
- 该模型成功地捕获了XLCEs的粘弹性行为.
- 风病学反应表明动态阴性秩序,网络弹性和链交换消散之间的相互作用.
- 在不同的测试条件下观察到有趣的风湿现象.
结论:
- 开发的模型提供了对 XLCE 行为的物理机制的洞察.
- 这项工作可以指导制造具有定制rheological属性的XLCEs.
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