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相关概念视频

Types Of Superconductors01:28

Types Of Superconductors

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A superconductor is a substance that offers zero resistance to the electric current when it drops below a critical temperature. Zero resistance is not the only interesting phenomenon as materials reach their transition temperatures. A second effect is the exclusion of magnetic fields. This is known as the Meissner effect. A light, permanent magnet placed over a superconducting sample will levitate in a stable position above the superconductor. High-speed trains that levitate on strong...
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Theory of Metallic Conduction01:17

Theory of Metallic Conduction

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The conduction of free electrons inside a conductor is best described by quantum mechanics. However, a classical model makes predictions close to the results of quantum mechanics. It is called the theory of metallic conduction.
In this theory, Newton's second law of motion is used to determine the acceleration of an electron in the presence of an applied electric field. Then, its velocity is expressed via this acceleration.
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Superconductor01:24

Superconductor

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A substance that reaches superconductivity, a state in which magnetic fields cannot penetrate, and there is no electrical resistance, is referred to as a superconductor. In 1911, Heike Kamerlingh Onnes of Leiden University, a Dutch physicist, observed a relation between the temperature and the resistance of the element mercury. The mercury sample was then cooled in liquid helium to study the linear dependence of resistance on temperature. It was observed that, as the temperature decreased, the...
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Ionic Bonding and Electron Transfer02:48

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Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions. 
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Semiconductors01:22

Semiconductors

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There is variation in the electrical conductivity of materials - metals, semiconductors, and insulators that are showcased with the help of the energy band diagrams.
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Ionic Crystal Structures02:42

Ionic Crystal Structures

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Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
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纳西康超离子导体的设计原则

Jingyang Wang1,2,3, Tanjin He1,2, Xiaochen Yang1,2

  • 1Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA, 94720, USA.

Nature communications
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新纳米超离子导体 (NASICON) 材料提供高离子导电性. 研究揭示了组成如何影响Na-ion导电性,指导优化固态电解质的设计.

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科学领域:

  • 材料科学 材料科学 材料科学
  • 固态化学 固态化学
  • 电化学 电化学 电化学

背景情况:

  • 纳米超离子导体 (NASICON) 材料由于其高离子导电性和稳定性,是重要的固态电解质.
  • 了解化学成分和离子导电性之间的关系是开发先进的储能解决方案的关键.

研究的目的:

  • 为了阐明化学成分如何影响纳西康材料中的Na-离子导电性.
  • 确定优化NASICON固态导体的设计标准.

主要方法:

  • 用第一原则计算来进行理论分析.
  • 进行NASICON材料的实验合成和电化学测试.
  • 采用自然语言驱动的文本挖掘NASICON离子导电性的历史数据.

主要成果:

  • 在新合成的NASICON中,在25°C时达到1.2mS cm−1的高离子导电性.
  • 发现离子导电性随着金属平均尺寸的增加而增加,并通过用SiO4.4.4替换PO4来增强.
  • 最佳的离子导电性接近每方程式单位3的Na含量,受其他组成变量的影响.

结论:

  • 含量主要通过影响激活屏障来增强离子导电性,而不是载体度.
  • 简单的设计标准为创建优化的NASICON导体提供了准则.
  • 取得了新的纳西康固态导体的成功合成和研究.