基于非富勒烯受体的有机太阳能电池中的电荷载体动力学:研究使用短暂吸收光谱学处理添加剂的影响
Gayoung Ham1, Damin Lee2, Changwoo Park2
1Department of Energy Convergence and Climate Change, Kyungpook National University, Daegu 41566, Republic of Korea.
Materials (Basel, Switzerland)
|August 26, 2023
概括
加工添加剂显著提高了有机太阳能电池中带有非富勒烯受体 (NFAs) 的电荷生成和载体寿命. 这提高了聚合物:NFA混合物的性能,为更高效的有机太阳能电池铺平了道路.
科学领域:
- 材料科学 材料科学 材料科学
- 太阳能光伏发电是如何实现的
- 有机电子 有机电子
背景情况:
- 大量异质连接有机太阳能电池 (OSC) 对可再生能源至关重要.
- 非富勒受体 (NFAs) 在OSC中提高了功率转换效率.
- 聚合物:NFA混合物的电荷生成机制需要进一步阐明.
研究的目的:
- 为了研究聚合物中的电荷生成机制:NFA混合物.
- 了解加工添加剂在增强电荷载体动态中的作用.
- 为了比较不同NFA (Y6和BTP-eC9) 在OSC中的表现.
主要方法:
- 暂时吸收 (TA) 光谱法用于研究电荷转移通路.
- 这项研究涉及了捐赠聚合物PM6与NFAs (Y6和BTP-eC9) 的混合物.
- 分析了含有加工添加剂和不含加工添加剂的膜.
主要成果:
- 整洁Y6和BTP-eC9的电荷载体寿命是可比的 (长达20 ns).
- PM6:BTP-eC9混合物显示出比PM6:Y6.6更高的电荷载体生成和更长的寿命.
- 加工添加剂显著增强了电荷载体的产生和延长了两种混合物的寿命.
结论:
- 在基于NFA的OSC中,加工添加剂对于优化充电生成和载体寿命至关重要.
- 操纵兴奋物种为改善OSC性能提供了一个有希望的途径.
- 这项工作促进了对聚合物中电荷转移的理解:NFA混合物用于高效的太阳能转换.
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