自愈和可再加工的弹性体,基于灵活应变传感器的伊胺-博洛克辛键
Peng Wang1, Zhuochao Wang2, Lu Liu1
1Department of Materials Science and Engineering, College of Mechanics and Materials, Hohai University, Nanjing 211100, China.
Molecules (Basel, Switzerland)
|August 26, 2023
概括
这项研究介绍了一种新的自愈弹性体,该弹性体由聚甲基 (PDMS) 制成,具有动态的胺基键和. 该材料快速愈合,可以再加工,从而实现先进的灵活电子.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
背景情况:
- 弹性体对于能源,电子和机器人技术至关重要.
- 开发自我修复和可再加工的弹性体是一个关键的挑战.
研究的目的:
- 为了创建一个双交叉连接的自我愈合的多氧弹性体.
- 研究其自我愈合,再加工和传感器应用.
主要方法:
- 用 imine 键和 boroxine 制造聚二甲基西洛 (PDMS) 网络.
- 评估机械性能,自我修复效率和再加工稳定性.
- 与碳纳米管 (CNT) 进行集成,以创建可伸缩的电传感器.
主要成果:
- 双交联PDMS弹性体在室温下在2小时内表现出快速和完全的机械强度恢复.
- 该材料在温和条件下表现出极好的再加工能力,而不会降低性能.
- 使用CNT的可伸缩,自我修复的电传感器已成功开发,用于实时监控人类运动.
结论:
- 动态伊米因键和氨酸的协同效应使得弹性体中具有卓越的自我愈合和再加工能力.
- 这项工作为开发用于柔性电子产品的先进的自我修复和可再加工的材料提供了有前途的途径.
相关概念视频
Elasticity
Elasticity is the ability of an object to withstand the effects of distortion and to return to its original size and shape once the forces causing deformation are removed. When an elastic material deforms under the action of an external force, it experiences internal resistance to the deformation. However, if no external force is applied, it returns to its original state.
The elasticity of an object can be described by a stress-strain curve, which represents the relationship between stress...
The elasticity of an object can be described by a stress-strain curve, which represents the relationship between stress...
Plastic Behavior
A material's elastic behavior is characterized by the disappearance of stress once the load is removed, allowing the material to return to its original state. However, when stress surpasses the yield point, yielding commences, marking the onset of plastic deformation or permanent set. This change from elastic to plastic behavior is influenced by the peak stress value and the duration before the load is removed. An intriguing observation occurs when a specimen is loaded, unloaded, and reloaded.
Circular Shafts - Elastoplastic Materials
The study of solid circular shafts under stress shows that within the elastic limit, stress increases directly to the distance from the shaft's center. This relationship holds until the shaft reaches a critical point of stress, beyond which it begins to yield, marking the transition from elastic to plastic deformation. At this crucial juncture, the maximum torque the shaft can endure without permanent deformation is determined, signifying the limit of its elastic behavior.
As torque on the...
As torque on the...
Members Made of Elastoplastic Material
The behavior of elastoplastic materials under bending stresses, particularly in structural members with rectangular cross-sections, is crucial for predicting material responses and understanding failure modes. Initially, when a bending moment is applied, the stress distribution across the section follows Hooke's Law and is linear and elastic. This distribution means the stress increases from the neutral axis to the maximum at the outer fibers, up to the elastic limit.
As the bending moment...
As the bending moment...
Elasticity in Concrete
Upon subjecting concrete to moderate or high uniaxial compressive or tensile stresses, the strain response is non-linear relative to the stress applied. As the stress is removed, the resulting stress-strain curve deviates from the original path traced during loading, creating a hysteresis loop, indicative of the concrete's non-linear and non-elastic properties. Typically, a material's modulus of elasticity, which is a measure of the material's stiffness, is inferred from the linear portion of...
Dynamic Modulus of Elasticity of Concrete
The dynamic modulus of elasticity assesses how a concrete structure deforms under impact or dynamic loads. It is typically higher than the static modulus of elasticity, measured under slow, steady loading conditions.
The sonic test is a common method to determine the dynamic modulus. In this test, a concrete beam, sized either 6 x 6 x 30 inches or 4 x 4 x 20 inches, is clamped at its center. Vibrations are initiated at one end of the beam by an electromagnetic exciter unit powered by a...
The sonic test is a common method to determine the dynamic modulus. In this test, a concrete beam, sized either 6 x 6 x 30 inches or 4 x 4 x 20 inches, is clamped at its center. Vibrations are initiated at one end of the beam by an electromagnetic exciter unit powered by a...


