基于BaO的烟火延迟组合2:不像预期的那样"绿色".
Kinga Lysien1, Klaudia Szatan2, Konrad Szydlo3
1Department of Physical Chemistry and Technology of Polymers, Silesian University of Technology, 44-100 Gliwice, Poland.
Molecules (Basel, Switzerland)
|August 26, 2023
概括
过氧化在烟火延迟组合 (PDC) 中显示出作为环保氧化剂的前景. 金属燃料的选择对PDC特性和燃烧行为产生重大影响.
科学领域:
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
- 燃烧科学 燃烧科学
背景情况:
- 烟火技术延迟组合 (PDC) 在各种应用中对控制时间至关重要.
- 开发环保的氧化剂是烟火技术的一个关键挑战.
- 过氧化 (BaO2) 为传统氧化剂提供了一个潜在的替代品.
研究的目的:
- 探索氧化作为PDCs的环保氧化剂.
- 分析新型PDCs的燃烧产物.
- 了解不同金属燃料 (Mg,Al,Fe,Cu) 如何影响PDC性能.
主要方法:
- 合成和描述包含过氧化的PDCs.
- 摩擦和冲击灵敏度的评估.
- 测量线性燃烧速度作为氧平衡 (OB) 的函数.
- 使用拉曼光谱和扫描电子显微镜与能量分散式X射线光谱 (SEM-EDS) 分析燃烧残留物.
主要成果:
- 开发的PDC显示了可接受的安全特性 (摩擦和冲击灵敏度).
- 线性燃烧速度成功与氧气平衡相关.
- 确定了燃烧产品的组成,为反应途径提供了洞察力.
- 阐明了金属燃料类型对PDC特性的影响.
结论:
- 过氧化是PDCs的可行的环保氧化剂.
- 金属燃料的选择显著影响PDC的燃烧特性.
- 基于实验证据,提出了这些PDC的初步燃烧机制.
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