设计用于防超级电容器的zwitterionic proline水凝电解质
Juan Zeng1, Hao Chen1, Liubing Dong2
1College of Chemistry and Environmental Engineering, Wuhan Polytechnic University, Wuhan 430023, China.
Journal of colloid and interface science
|August 26, 2023
概括
兹威特烯添加剂防止水凝电解质结冰,在零度以下的温度下保持高离子导电性. 这一突破使得强大的,抗储能装置,如超级电容器,可以在极端条件下使用.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 聚合物化学 聚合物化学
背景情况:
- 由于水结,水凝电解质在零度以下的温度下面临性能限制,这大大降低了离子导电性.
- 这种结问题阻碍了水凝电解质在寒冷环境中的实际应用.
研究的目的:
- 开发一种新型的抗水凝电解质,在零下温度下具有高离子导电性.
- 研究zwitterionic proline作为增强低温性能的添加剂的作用.
主要方法:
- 在水凝电解质配方中加入zwitterionic proline.
- 在各种零下温度下测量离子导电性.
- 超级电容器的电化学性能测试使用开发的水凝电解质,包括特定电容和低温循环稳定性.
主要成果:
- 烯基水凝电解质表现出高离子导电性 (4.2 mS cm-1),即使在-40°C.
- 超级电容器在25°C时表现出高特异容量145.8Fg-1和在-30°C时表现出高特异容量116.1Fg-1.
- 超级电容器在-12000次在-30°C下循环后保持了71%的容量保留,表明出色的低温稳定性.
结论:
- 兹威特烯有效地防止水凝电解质的结,并在零度以下的温度下保持高离子导电性.
- 开发的防水凝电解质显示出对低温储能应用的显著前景.
- 这项研究为在极寒条件下运行的可靠储能装置开辟了新的可能性.
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