基于天然奇多的碳点作为一种环保和有效的腐蚀抑制剂,用于在HCl溶液中的温钢
Deshuai Zhen1, Shaoqi Zhang2, Xinyu Zhang2
1School of Public Health, Hengyang Medical School, University of South China, Hengyang, Hunan 421001, PR China; Engineering Research Center of Loss Efficacy and Anticorrosion of Materials of Guizhou, School of Chemistry and Chemical Engineering, Qiannan Normal University for Nationalities, Duyun, Guizhou 558000, PR China; State Key Laboratory for Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha, Hunan 410082, PR China.
International journal of biological macromolecules
|August 26, 2023
概括
环保的基托基碳点 (CA-CDs) 有效地抑制了HCl中温和钢的腐蚀. 这些新型纳米粒子通过结合化学吸收和物理阻断机制,达到97.4%的效率.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 腐蚀科学 腐蚀科学
背景情况:
- 在酸性介质中对温和钢的腐蚀对工业构成重大挑战.
- 开发高效和环保的腐蚀抑制剂至关重要.
- 基托衍生的碳点为材料保护提供了有前途的特性.
研究的目的:
- 为了合成和描述基托基碳点 (CA-CDs).
- 评估CA-CDs作为1.0M HCl中温钢的腐蚀抑制剂的有效性.
- 为了阐明CA-CDs的腐蚀抑制机制.
主要方法:
- 通过激光切除基托和L-histidine合成CA-CDs.
- 使用FT-IR,UV-vis,拉曼,XRD,TEM和XPS进行表征.
- 通过减肥,电化学测量 (潜在动力极化,EIS),SEM,AFM和XPS分析进行腐蚀抑制评估.
主要成果:
- CA-CDs被成功合成和表征.
- 对于温钢而言,CA-CDs表现出极好的腐蚀抑制,在40毫克L-1.1下达到97.4%的效率.
- 抑制后的混合类型行为,与兰迈尔吸附同热法 (化学吸收和物理吸收) 一致.
结论:
- CA-CD是HCl中温钢的有效,环保的腐蚀抑制剂.
- 抑制机制涉及协同化学吸收和物理吸收.
- CA-CDs为轻钢防酸腐蚀提供了一个可行的解决方案.
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