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相关概念视频

Ionic Crystal Structures02:42

Ionic Crystal Structures

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Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
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Nuclear Localization Signals and Import01:46

Nuclear Localization Signals and Import

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Proteins targeted to the nucleus carry short stretches of amino acid sequences called the nuclear localization signal or NLS. Classical nuclear localization signals are of two types: monopartite and bipartite NLS. Monopartite classical NLS (cNLS) consists of a single cluster of 4-8 amino acids. Bipartite cNLS consists of two clusters of  2-3 amino acids and a 9-12 residue long proline-rich linker bridging the two clusters. Signal clusters are rich in positively charged amino acids such as...
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Ladder Diagrams: Complexation Equilibria01:07

Ladder Diagrams: Complexation Equilibria

370
Ladder diagrams are useful for evaluating equilibria involving metal-ligand complexes. The vertical scale of the ladder diagram represents the concentration of unreacted or free ligand, pL. The horizontal lines on the scale depict the log of stepwise formation constants for metal-ligand complexes and indicate the dominant species in all the regions.
The formation constant, K1, for the formation of Cd(NH3)2+ complex from cadmium and ammonia is 3.55 × 102. Log K1 (i.e. pNH3) is 2.55, and...
370
Lumber Defects01:23

Lumber Defects

148
Lumber defects, which can affect both the appearance and structural integrity of wood, include a variety of growth and manufacturing flaws. Growth defects such as knots and knotholes occur where branches were once attached to the tree trunk, with knotholes forming when these knots fall out. Other natural defects include decay and insect damage, which compromise the wood's strength and durability.
Shakes are minor fractures that run along or across the wood's annual rings, while wane is...
148
Minerals01:26

Minerals

356
Minerals are essential nutrients that the human body needs in small amounts to work properly. They play a vital role in many bodily functions, such as building strong bones and transmitting nerve impulses. Some minerals are needed for hormone production or to maintain a normal heartbeat. Major minerals include calcium, phosphorus, potassium, sulfur, sodium, chlorine, and magnesium, while trace minerals include iron, manganese, copper, iodine, zinc, cobalt, fluoride, and selenium.
 
Major...
356
Structures of Solids02:22

Structures of Solids

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Solids in which the atoms, ions, or molecules are arranged in a definite repeating pattern are known as crystalline solids. Metals and ionic compounds typically form ordered, crystalline solids. A crystalline solid has a precise melting temperature because each atom or molecule of the same type is held in place with the same forces or energy. Amorphous solids or non-crystalline solids (or, sometimes, glasses) which lack an ordered internal structure and are randomly arranged. Substances that...
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相关实验视频

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Molten-Salt Synthesis of Complex Metal Oxide Nanoparticles
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Molten-Salt Synthesis of Complex Metal Oxide Nanoparticles

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在La-Na-N系统中缺陷岩盐结构.

Yao Yuan1, Simon D Kloß2, J Paul Attfield1

  • 1Centre for Science at Extreme Conditions and School of Chemistry, University of Edinburgh, Peter Guthrie Tait Road, Edinburgh EH9 3FD, UK.

Philosophical transactions. Series A, Mathematical, physical, and engineering sciences
|August 27, 2023
PubMed
概括

亚化在高压下与化反应,形成新的缺陷岩盐化. 这些发现扩展了已知的La-Na-N三元系统,揭示了新材料合成的潜力.

科学领域:

  • 材料科学 材料科学 材料科学
  • 固态化学 固态化学
  • 高压合成高压合成

背景情况:

  • 亚化 (NaN3) 是合成新型化物的主要源.
  • 高压和高温条件对于探索新材料相来说至关重要.

研究的目的:

  • 在高压条件下调查La-Na-N三元系统.
  • 通过使用化作为源来合成和描述新的化相.

主要方法:

  • 化和化之间的高压和高温反应.
  • 粉末X射线衍射 (PXRD) 用于初步结构确定.

主要成果:

  • 在La-Na-N系统中发现了两种新的岩盐相缺陷.
  • 具有不同含量的La1−xNaxN的表征,显示四角形和立方形结构.
  • 同时存在的立方相的识别,暂时被指定为"NaN1/3",稳定由.

结论:

  • 高压La-Na-N相位图富含有缺陷的岩盐材料.
  • 需要进一步的研究,包括中子衍射,才能确定结构.
  • 这项研究为在极端条件下合成复杂化物开辟了道路.
关键词:
高压化学 高压化学化物 化物 化物结构阐明 结构阐明

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