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相关概念视频

Batteries and Fuel Cells03:12

Batteries and Fuel Cells

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A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
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Electrolysis03:00

Electrolysis

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In a galvanic cell, the electrical work is done by a redox system on its surroundings as electrons produced by the spontaneous redox reactions are transferred through an external circuit. Alternatively, an external circuit does work on a redox system by imposing a voltage sufficient to drive an otherwise nonspontaneous reaction in a process known as electrolysis. For instance, recharging a battery involves the use of an external power source to drive the spontaneous (discharge) cell reaction in...
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Electrolyte and Nonelectrolyte Solutions02:21

Electrolyte and Nonelectrolyte Solutions

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Substances that undergo either a physical or a chemical change in solution to yield ions that can conduct electricity are called electrolytes. If a substance yields ions in solution, that is, if the compound undergoes 100% dissociation, then the substance is a strong electrolyte. Complete dissociation is indicated by a single forward arrow. For example, water-soluble ionic compounds like sodium chloride dissociate into sodium cations and chloride anions in aqueous solution.
63.2K
Molecular and Ionic Solids02:54

Molecular and Ionic Solids

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Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
17.2K
Ionic Bonding and Electron Transfer02:48

Ionic Bonding and Electron Transfer

41.7K
Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions. 
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Ionic Strength: Effects on Chemical Equilibria01:19

Ionic Strength: Effects on Chemical Equilibria

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The addition of an inert ionic compound increases the solubility of a sparingly soluble salt. For example, adding potassium nitrate to a saturated solution of calcium sulfate significantly enhances the solubility of calcium sulfate. Le Châtelier's principle cannot predict this shift in the equilibrium. Instead, this could be explained in terms of changes in the effective concentration of the ions in solution in the presence of added inert salt.
In this solution, the primary...
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相关实验视频

Updated: Jul 18, 2025

Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
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普鲁士蓝型离子导体固体电解质用于所有固态电池.

Taewon Kim1, Sang Hyeok Ahn1, You-Yeob Song2

  • 1School of Energy and Chemical Engineering, Ulsan National Institute of Science and Technology (UNIST), Ulsan, 44919, Republic of Korea.

Angewandte Chemie (International ed. in English)
|August 28, 2023
PubMed
概括

普鲁士蓝色模拟器 (PBA) 开放框架显示为全固态电池的固体电解质具有前途,提供良好的离子导电性. -PBA展示了最高的导电性和稳定的循环性能.

关键词:
所有固态电池都是固态电池六亚诺酸盐是的六亚诺酸盐.离子电池的使用方法普鲁士蓝色类似的东西固体电解质是一种固体电解质.

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Characterization of Electrode Materials for Lithium Ion and Sodium Ion Batteries Using Synchrotron Radiation Techniques
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Elemental-sensitive Detection of the Chemistry in Batteries through Soft X-ray Absorption Spectroscopy and Resonant Inelastic X-ray Scattering
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相关实验视频

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Characterization of Electrode Materials for Lithium Ion and Sodium Ion Batteries Using Synchrotron Radiation Techniques
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Elemental-sensitive Detection of the Chemistry in Batteries through Soft X-ray Absorption Spectroscopy and Resonant Inelastic X-ray Scattering
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Elemental-sensitive Detection of the Chemistry in Batteries through Soft X-ray Absorption Spectroscopy and Resonant Inelastic X-ray Scattering

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科学领域:

  • 材料科学 材料科学 材料科学
  • 电化学 电化学 电化学
  • 固态化学 固态化学

背景情况:

  • 传统的固体电解质面临H2S气体演化和高成本等局限性.
  • 现有的硫化物,氧化物和化物电解质有气体演变,成本和接触不良的问题.

研究的目的:

  • 引入普鲁士蓝模拟 (PBA) 开放框架结构作为新型固体电解质.
  • 为了研究Na+导电性和PBA晶格参数之间的关系.
  • 探索PBA在全固态电池中的潜力.

主要方法:

  • 五种PBA材料的合成和表征.
  • 测量Na+导电性的方法.
  • 使用放松时间分布和密度函数理论 (DFT) 计算进行分析.
  • 可行性测试,包括循环性能.

主要成果:

  • PBA 具有显著的 Na+ 导电性 (>10−2 mS cm−1).
  • Mn-PBA获得了9.1×10−2 mS cm−1.1. 的最高Na+导电性.
  • 在0.2C时,Mn-PBA显示出极好的循环保留率 (95.1%在80个循环后).

结论:

  • PBA开放框架是所有固态电池的可行的固体电解质.
  • 调节格子参数通过改变离子框架相互作用来影响Na+导电性.
  • -PBA为下一代固态电池提供了一个有希望的候选.