使用生物基异质催化剂从棕油中提高脂肪酸甲基的可持续生产:过程模拟和技术经济分析
Phonsan Saetiao1, Napaphat Kongrit1, Jakkrapong Jitjamnong1
1Petroleum Technology Program, Industrial Technology Department, Faculty of Industrial Education and Technology, Rajamangala University of Technology Srivijaya, 2/1 Rachadamnoennork Rd., Boryang, Muang, Songkhla 90000, Thailand.
从子灰 (CSA) 制成的新型固体碳催化剂有效地生产生物柴油. 这种可持续的催化剂在最佳条件下实现了97.14%的收益率,显示出经济可行性和减少二氧化碳排放.
科学领域:
- 绿色化学和催化剂的研究
- 可再生能源可再生能源来源
- 材料科学 材料科学 材料科学
背景情况:
- 生物柴油合成依赖于高效和可持续的催化剂.
- 传统的催化剂往往涉及同质的系统与分离的挑战.
- 农业废物如子的利用对循环经济至关重要.
研究的目的:
- 开发和优化生物柴油生产的可持续固体碳催化剂.
- 研究开发的催化剂的可重复使用性和局限性.
- 评估该过程的技术经济可行性和环境影响.
主要方法:
- 使用带有碳酸 (K2CO3) 的溶解性子灰 (CSA) 制备固体碳催化剂.
- 使用响应表面方法 (RSM) 和中央复合材料设计优化转化过程.
- 评估催化剂性能,可重复使用性,技术经济可行性和环境影响 (全球变暖潜力).
主要成果:
- 最佳的催化剂组成是30重量%K2CO3/CSA.
- 在优化条件下,可获得97.14%的生物柴油,催化剂负荷为3.27%的重量,甲醇:油比为9.98:1,在65°C下74分钟.
- 催化剂在四个循环中证明了可重复使用性,尽管离子漏导致产量下降.
- 技术经济分析显示了积极的NPV (516万美元) 和IRR (44.2%).
- 与传统方法 (1784.6/年) 相比,生物柴油生产的二氧化碳排放量较低 (1401.86/年).
结论:
- 开发的K2CO3/CSA催化剂是高效生物柴油合成的有希望的可持续选择.
- 该过程在经济上是可行的,并且由于减少二氧化碳排放而对环境有利.
- 建议进一步研究减轻催化剂出,以提高长期稳定性.
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