与硫的相互作用诱导了纯形式amidinium三化物中的湿度和水稳定性
Muhammed P U Haris1, Eliseo Ruiz2, Samrana Kazim1,3
1BCMaterials, Basque Center for Materials, Applications, and Nanostructures, UPV/EHU Science Park, 48940 Leioa, Spain.
概括
研究人员使用一种新的含硫添加剂稳定了formamidinium lead triiodide (FAPI) 矿薄膜. 这一策略可以防止相位过渡,并增强抗潮湿和老化的稳定性,这对于矿太阳能电池应用至关重要.
科学领域:
- 材料科学 材料科学 材料科学
- 固态化学 固态化学
- 太阳能光伏发电是如何实现的
背景情况:
- 甲三化 (FAPI) 矿薄膜对太阳能电池有希望,但患有相位不稳定性.
- 纯FAPI矿易过渡到非矿2H阶段,限制了设备的性能和寿命.
研究的目的:
- 制定一种策略,以稳定FAPI矿薄膜,防止相位过渡.
- 为了提高FAPI矿膜在各种环境压力下的运行稳定性.
主要方法:
- 一种含有硫异原子的多功能氨盐添加剂被引入到FAPI矿薄膜中.
- 用实验性表征和理论研究来研究稳定机制.
- 分析包括评估结晶性,谷物形态,面向和在湿度和老化下稳定性的评估.
主要成果:
- 含硫的添加剂成功地将热力学稳定性从2H阶段转移到接近所需立方相的中间阶段.
- 实现了高晶度和微米大小的颗粒,具有首选的 (00h) 面向.
- Pb...S 相互作用有效地减轻了因高相对湿度,直接暴露于水和保质期老化的降解.
结论:
- 拟议的添加剂化战略有效地稳定了FAPI矿薄膜,克服了关键的相位过渡问题.
- Pb...S 相互作用在稳定矿立方相和保持静态度完整性方面发挥着关键作用.
- 这项工作为提高FAPI矿基设备的耐用性和可靠性提供了一条途径.
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