雷利裂变过程的动力学 在 ∼100 nm 充电的水性纳米滴中
Emeline Hanozin1, Conner C Harper1, Matthew S McPartlan1
1Department of Chemistry, University of California, Berkeley, California 94720, United States.
ACS central science
|August 28, 2023
概括
研究人员使用电喷射和质谱学研究了带电纳米滴的分解. 他们观察到,雷利极限以上的带电纳米滴经历裂变,产生不同数量和大小的较小滴.
科学领域:
- 物理化学 物理化学
- 体科学 体科学 体科学
- 质谱测量质量谱测量
背景情况:
- 滴滴裂变在自然和工业过程中至关重要.
- 微米尺寸滴滴的裂变动力学是已知的,但纳米尺寸滴滴的行为不太了解.
- 电子喷雾是一种产生带电液滴的方法.
研究的目的:
- 为了研究单个水性纳米滴的自发裂变动态.
- 了解电喷液形成的带电纳米滴的分解过程.
- 为了描述由纳米滴裂变产生的后代滴.
主要方法:
- 使用电荷检测质谱分析单个纳米滴.
- 通过电子喷雾产生水性纳米滴.
- 随着时间的推移观察自发裂变事件.
主要成果:
- 在雷利极限以上观察到充电的水性纳米滴的自发裂变.
- 裂变过程从在2毫秒内产生两个后代滴到在100+毫秒内产生数十个后代滴不等.
- 后代液滴表现出广泛的电荷,质量和数量.
结论:
- 纳米滴的雷利裂变是一个连续的过程谱.
- 后代滴的数量,质量和电荷是高度可变的.
- 这些发现有助于我们更好地理解纳米尺度滴滴裂变.
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