在聚合物玻璃中,在变形时,结合方位决定的内体应力
Tingyu Xu1, Kunpeng Cui2, Cui Nie1
1National Synchrotron Radiation Lab, Anhui Provincial Engineering Laboratory of Advanced Functional Polymer Film, CAS Key Laboratory of Soft Matter Chemistry, University of Science and Technology of China, Hefei 230026, China.
ACS macro letters
|August 29, 2023
概括
聚合物玻璃的机械刺激揭示了收缩应力和结合层面的细分方向之间的直接联系. 这一发现揭示了一种影响聚合物的机械行为的新压力机制.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物物理 聚合物物理
- 计算材料科学科学 计算材料科学
背景情况:
- 聚合物玻璃的机械性能取决于多个尺度的复杂分子间和链内结构.
- 将这些结构与宏观机械行为联系在一起的精确机制仍然不完全理解.
研究的目的:
- 研究聚合物玻璃中机械刺激和结构变化的关系.
- 阐明链内分段定向在键尺度上的机械性质上的作用.
主要方法:
- 利用计算模拟来对冷拉聚合物玻璃施加机械刺激.
- 分析了诱导收缩应力和分段方向参数在链内债券水平之间的相关性.
主要成果:
- 收缩应力和在链内连接键尺度上的段向参数之间确定了直接的一对一对应.
- 在共存的细分方向和粒子流动性条件下,证明了一种新型体应激的出现.
结论:
- 在键级上的链内定位显著影响了聚合物玻璃的机械行为.
- 提出了一种潜在的机制,涉及体应力,以了解债券水平方向如何影响宏观机械性质.
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