动态结合诱导的粘性摩擦量身定制非牛顿式的类风湿学
Hojin Kim1,2, Mike van der Naald1, Neil D Dolinski2
1James Franck Institute and Department of Physics, The University of Chicago, Chicago, Illinois 60637, USA. jaeger@uchicago.edu.
这项研究引入了动态化学桥梁,在密集的悬浮中创建可调节的"粘性"摩擦. 这种新的方法控制了非牛顿流体的时间依赖性流体学,为材料设计提供了新的可能性.
科学领域:
- 材料科学 材料科学 材料科学
- 类风病学 类风病学 类风病学
- 聚合物化学 聚合物化学
背景情况:
- 密集的悬挂表现出非牛顿式剪切加厚行为.
- 目前的模型侧重于粒子间摩擦,在切割停止后立即消失.
- 需要具有可调节的持久性和大小的摩擦机制.
研究的目的:
- 为了研究在密集悬浮中的颗粒之间由动态化学桥梁引起的摩擦.
- 探索这种"粘性"摩擦对非牛顿流体的时间依赖性风学的影响.
- 通过定制化学相互作用来证明对质性质的控制.
主要方法:
- 使用密集悬浮的醇功能化颗粒和二聚合物与甲胺末端组的密集悬浮.
- 采用无催化剂,室温动态的-迈克尔反应,在粒子之间形成可逆的共价键.
- 系统地改变参数,如部分的电子性质,聚合物分子量,竞争性粘合剂度和温度.
主要成果:
- 动态化学桥梁创造了一个持久的,可调节的摩擦,模仿物理摩擦,但更粘.
- 这种"粘性"的摩擦会导致可调节的氧化 (依赖时间的粘度变化).
- 化学和物理参数的系统变化允许精确控制悬浮液的风湿反应.
结论:
- 动态共价键可以被设计为诱导可控制的,依赖于时间的摩擦在密集的悬浮.
- 这种化学摩擦机制为定制非牛顿流体行为提供了一个新的范式.
- 通过化学设计,这些发现可以精确控制悬浮体质的时间依赖性.
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