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Updated: Jul 17, 2025

Solid-phase Synthesis of [4.4] Spirocyclic Oximes
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通过α-C(sp3) -H功能化/激进循环化级联进行含有S,N,O的多重环的光化学合成

Shi-Yan Cheng1, Jia-Bin Liao1, Yu-Mei Lin1

  • 1Key Laboratory of Chemical Biology of Fujian Province, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China.

Organic letters
|August 30, 2023
PubMed
概括

一种新的有机光触媒方法通过激进循环化合成复杂的三环异环. 这种高效的过程提供了出色的选择性和创造新的异环药物的潜力.

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Radicals, the highly reactive species, gain stability by undergoing three different reactions. The first reaction involves a radical-radical coupling, in which a radical combines with another radical, forming a spin‐paired molecule. The second reaction is between a radical and a spin‐paired molecule, generating a new radical and a new spin‐paired molecule. The third reaction is radical decomposition in a unimolecular reaction, forming a new radical and a spin‐paired...
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