通过光学发射光谱学测定在化物中的数量,使用一种新的盐电极微等离子体源
Zhaoqing Cai1, Huixiu Chen2, Meng Gao1
1Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, 201899, China; Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing, 100049, China.
Talanta
|August 30, 2023
概括
一个新的盐电极微等离子体 (MSEMP) 源使光学发射光谱学 (OES) 能够分析盐和固体. 这种微等离子技术提供了精确的元素量化,即使在具有挑战性的样本矩阵中.
科学领域:
- 分析化学 分析化学
- 等离子体物理学的物理学
- 材料科学 材料科学 材料科学
背景情况:
- 光学发射光谱 (OES) 是一种强大的分析技术.
- 分析融盐和固体样本对OES提出了独特的挑战.
- 微等离子体来源为专门的分析应用提供了潜力.
研究的目的:
- 为OES开发和评估一种新的盐电极微等离子体 (MSEMP) 源.
- 评估MSEMP-OES用于融盐的元素分析的能力.
- 探索MSEMP-OES在固体样本分析方面的潜力.
主要方法:
- 使用盐电极和供应的空心管计数电极建造了一种新的MSEMP源.
- 通过获得特征光谱线,对化物样本进行定性元素分析的评估.
- 在发光放电中对固体铜溶解和激发的评估.
- 研究盐温度和组成对分析的影响.
- 在盐矩阵中精确量化.
主要成果:
- 成功获得化物样本中元素的特征光谱线,证明了良好的定性分析能力.
- 通过溶解和激发固体铜来进行固体样本分析的证明潜力.
- 证实,盐的温度和成分不会影响的反应.
- 在盐样本中实现了精确的量化.
结论:
- 开发的MSEMP-OES对于融盐的定性和定量元素分析是有效的.
- 该MSEMP来源显示出对固体样本的现场分析有前途.
- 这项研究推动了微等离子体技术的应用,用于分析具有挑战性和特殊样本.
相关概念视频
Flame Photometry: Lab
274
In a flame photometer, when a solution like potassium chloride is aspirated into the flame, the solvent evaporates, leaving behind dehydrated salt. This salt dissociates into free gaseous atoms in their ground state. Some of these atoms absorb energy from the flame, leading to their excitation. The excited atoms return to the ground state, emitting photons at characteristic wavelengths. Because only electronic transitions are involved, the resulting emission lines are very narrow. The intensity...
274
Atomic Emission Spectroscopy: Lab
197
AES is a powerful analytical technique, especially effective when used with plasma sources, producing abundant spectra in characteristic emission lines. The Inductively Coupled Plasma (ICP), in particular, yields superior quantitative analytical data due to its high stability, low noise, low background, and minimal interferences under optimal experimental conditions. However, newer air-operated microwave sources are emerging as promising alternatives that could be more cost-effective than...
197
Flame Photometry: Overview
659
Flame photometry, also known as flame emission spectrometry, is a technique used for the qualitative and quantitative analysis of elements present in a sample using a flame as the source of excitation energy. The concept of flame photometry was realized in the early 1860s by Kirchhoff and Bunsen, who discovered that specific elements emit characteristic radiation when excited in flames. The first instrument developed for this purpose was used to measure sodium (Na) in plant ash using a Bunsen...
659
Inductively Coupled Plasma Atomic Emission Spectroscopy: Principle
695
Inductively coupled plasma (ICP) is the most widely used plasma source in atomic emission spectroscopy (AES), also known as Inductively Coupled Plasma Optical Emission Spectroscopy (ICP-OES). The ICP source, or torch, consists of three concentric quartz tubes with argon gas flowing through them. A spark from a Tesla coil initiates the ionization of argon, generating a high-temperature plasma.
The ions and electrons produced interact with the fluctuating magnetic field created by a water-cooled...
The ions and electrons produced interact with the fluctuating magnetic field created by a water-cooled...
695
Atomic Emission Spectroscopy: Instrumentation
522
The instrumentation of atomic emission spectrometry (AES) involves various components, including atomization devices that convert samples into gas-phase atoms and ions. There are two main types of atomization devices: continuous and discrete atomizers. Continuous atomizers, like plasmas and flames, introduce samples in a constant stream, while discrete atomizers inject individual samples using syringes or autosamplers. The most common discrete atomizer is the electrothermal atomizer.
522
Photoluminescence: Applications
429
Photoluminescence offers a wide range of applications due to its inherent sensitivity and selectivity. This technique allows for both direct and indirect analyses of the analyte. Direct quantitative analysis is possible when the analyte exhibits a favorable quantum yield for fluorescence or phosphorescence. However, an indirect analysis may be feasible if the analyte is not fluorescent or phosphorescent, or if the quantum yield is unfavorable. Indirect methods include reacting the analyte with...
429


